Mossbauer Spectroscopy of [N (CH_3)_4]_2FeCl_4

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概要

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• NI6ssbatrer spectrttrn of "Fe of IN(CH3),l]2FQCl.l w?rs ta'xeastrred as a f'tnnction of tenaperatvtreIll tlue tertajcerattrre raxnge 20 N 290 K. Siragle dotrblet xvas observed in the orthorhotaabic ph;tse(Pl12lSC I). Tlae spectrtruaa is atltaaost the sanae ita tlae incornnaaensurate phase (phase II) and inthe phase II' xvlaere the strttcttrre is tnodtrlated in the z-direction with tlae waxzentrraaber 3/7.These ta?odtr[atiora seezaas to raise no large EFG (electric field gradient) rtaodtrJation to C2t.L1SCnoticealcle cluatnge in the spectrtrrt?. A nexv dotz}vlet 2lPP62lI,S in the phase III xvlaere tlae strtncttureis cotaatnenstzratte xvith tlae cell tripling along tlae c axis. This dotrblet persists even to tlae phaseIV where the strtrcttrre is rauotaoclinic x'x'it1? Z :::: 4. If' we consider the crystal syunrnetry, theextra dotrblet is prolnibited in this phase. The extra EFG is iraterpreted 21S the pectrliarity to thepoxvder S21l11P1(2.

• 社団法人日本物理学会の論文
• 1998-08-15

著者

• HIKITA Tomoyuki

  Department of Applied Physics,Faculty of Engineering,Tohoku University

• Hikita T

  Tohoku Univ. Miyagi

• Hikita Tomoyuki

  Department Of Applied Physics Faculty Of Engineering Tohoku University

• Hikita Tomoyuki

  Department Of Applied Physics.faculty Of Engineering Tohoku University

• ITOH Kazuo

  Laboratory of Physical Science,College of Science and Technology,Nihon University

• GESI Kazuo

  Department of Materials Science,College of Science and Technology,Iwaki Meisei University

• Gesi K

  Iwaki Meisei Univ. Fukushima

• Gesi Kazuo

  Department Of Materials Science College Of Science And Technology Iwaki Meisei University

• Gesi Kazuo

  Department Materials Science College Of Science And Engineering Iwaki Meisei University

• Itoh Kazuo

  Laboratory Of Physical Science College Of Science And Technology Nihon University

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