Crystal Structure of NH_3CH_2COOHH_2PO_3 in the Ferroelectric Phase
スポンサーリンク
概要
- 論文の詳細を見る
X-ray investigation was carried out to examine the ferroelectric phase transition in glycinium phosphite, NH_3CH_2COOHH_2PO_3,from the structural point of view. The result indicates that the crystal belongs to the space group P2_1 in the ferroelectric phase and the unit cell parameters obtained at 198 K are a=9.758 (2) Å, b=8.510 (1) Å, c=7.375 (1) Å and β=100.47 (1)°. The crystal structure in ferroelectric phase was determined using an automatic four-circle diffractometer and refined to R=0.032 and R_w=0.023 for 2685 independent reflections. Structure analysis clarified that in the ferroelectric phase, the hydrogen atoms between neighboring phosphite tetrahedra are in the ordered state and phosphite tetrahedra deform from those in the paraelectric phase.
- 社団法人日本物理学会の論文
- 2002-02-15
著者
-
SHIKANAI Fumihito
Department of Applied Physics, Faculty of Science, Science University of Tokyo
-
KOMUKAE Masaru
Department of Applied Physics, Faculty of Science, Science University of Tokyo
-
OSAKA Toshio
Department of Applied Physics, Faculty of Science, Science University of Tokyo
-
Czapla Z
Institute Of Experimental Physics University Of Wroclaw
-
Osaka T
Tokyo Univ. Sci. Tokyo
-
Osaka Toshio
Department Of Applied Physics Faculty Of Science Tokyo University Of Science
-
Osaka Toshio
Department Of Applied Physics Faculty Of Science Science University Of Tokyo
-
Komukae M
Tokyo Univ. Sci. Tokyo
-
Komukae Masaru
Department Of Applied Physics Faculty Of Science Science University Of Tokyo
-
Komukae M
Department Of Applied Physics Faculty Of Science Tokyo University Of Science
-
Czapla Zbigniew
Institute Of Experimental Physics University Of Wroclaw
-
Shikanai Fumihito
Department Of Applied Physics Faculty Of Science Tokyo University Of Science
関連論文
- 23pHS-5 対称性から予測されるβ-R_2(MoO_4)_3のマルチフェロイック特性(23pHS 誘電体(マルチフェロイック・ドメイン),領域10(誘電体,格子欠陥,X線・粒子線,フォノン))
- Nb_3Sn線材における事前曲げ効果の Deviatoric strain model に基づく解釈
- 28aYJ-8 プロトン伝導体K_3H(SeO_4)_2のSeO_4四面体の動的振る舞いIV(誘電体(TGS・硫安系),領域10,誘電体,格子欠陥,X線・粒子線,フォノン物性)
- 23pYK-8 パルス中性子を用いたY_3Al_5O_の単結晶構造解析(23pYK X線・粒子線(中性子),領域10(誘電体,格子欠陥,X線・粒子線,フォノン物性))
- 22pTE-12 (Pb,Sr)TiO_3ナノパウダーの構造解析(誘電体(酸化物系),領域10,誘電体,格子欠陥,X線・粒子線,フォノン物性)
- 27pRF-9 プロトン伝導体K_3H(SeO_4)_2のSeO_4四面体の動的振る舞いIII(27pRF 誘電体(水素結合系),領域10(誘電体,格子欠陥,X線・粒子線,フォノン物性))
- 30pXD-3 J-PARCに向けてのパルス中性子源を用いた単結晶構造解析の評価と展望(30pXD X線・粒子線(中性子・粒子線),領域10(誘電体,格子欠陥,X線・粒子線,フォノン物性))
- 30aYA-5 K_3H(SeO_4)_2の中性子準弾性散乱(30aYA 誘電体,領域10(誘電体,格子欠陥,X線・粒子線,フォノン物性))
- 24aYE-1 プロトン伝導体K_3H(SeO_4)_2のSeO_4四面体の動的振る舞いII(誘電体(水素結合),領域10,誘電体,格子欠陥,X線・粒子線,フォノン物性)
- 21pXA-3 プロトン伝導体K_3H(SeO_4)_2のSeO_4四面体の動的振る舞いI(誘電体(水素結合系),領域10,誘導体,格子欠陥,X線・粒子線,フォノン物性)
- 中性子回折・散乱から見たプロトン伝導体K_3H (SeO_4)_2
- Pressure Effect on the Phase Transition in (CH_3)_2NH_2H_2PO_4
- Pressure Effect on the Phase Transition in (CH_3)_2NH_2H_2AsO_4 and Its Isotope Effect
- 21pVE-2 (K_Rb_x)_3H(SeO_4)_2の中性子粉末構造解析(21pVE 誘電体(水素結合系),領域10(誘電体,格子欠陥,X線・粒子線,フォノン物性))
- Neutron Diffraction Study of Crystal Structures of Deuterated Glycinium Phosphite in Paraelectric and Ferroelectric Phases(Condensed Matter : Structure, Mechanical and Thermal Properties)
- Neutron Diffraction Study of Crystal Structures of Deuterated Glycinium Phosphite in Paraelectric and Ferroelectric Phases
- Ferroelastic Phase Transition in TIH_2PO_4
- Ferroelectricity of CsRbSeO_4
- Dielectric Study of the Phase Transition in K_3H (SeO_4)_2 and Isotope Effect
- Evidence for Weak-Ferroelectricity of (NH_4)_2ZnCl_4 in the Phase between Ferro- and Antiferro-Electric Phases
- Structural Study of Ferroelastic TlH_2PO_4
- Structural Study of Partially Deuterated Glycinium Phosphite in the Paraelectric Phase
- 22pTE-13 (Pb_Sr_)TiO_3ナノ粒子におけるフォノン閉じ込め効果(誘電体(酸化物系),領域10,誘電体,格子欠陥,X線・粒子線,フォノン物性)
- 23pWY-9 対称性から予測されるβ-R_2(MoO_4)_3のマルチフェロイック特性II(23pWY マルチフェロイック・リラクサー,領域10(誘電体格子欠陥,X線・粒子線フォノン))
- 25pYE-9 (Pb, Sr)TiO_3ナノパウダーの構造解析II(誘電体(酸化物系),領域10,誘電体,格子欠陥,X線・粒子線,フォノン物性)
- 事前曲げ処理を行ったCuNb補強Nh_3Sn線材の中性子回折による歪測定
- X-Ray Diffraction Study on a New Incommensurate Phase Transition in Ferroelectric (NH_4)_2ZnCl_4
- X-Ray Diffraction Study on a New Incommensurate Phase Transition in Ferroelectric (NH_4)_2ZnBr_4
- Effect of Hydrostatic Pressure on the Ferroelectric Phase Transition in N_2H_5Al (SO_4)_2・12H_2O
- Dielectric Dispersion in Ferroelectric N_2H_5Al(SO_4)_2・12H_2O
- Dielectric Property in NH_3OHAl(SO_4)_2・12H_2O
- Ferroelectricity in N_2H_5Al(SO_4)_2・12H_2O
- Acoustic phonons and a central mode in the protonic conductor K3H(SeO4)2
- Study of the Ferroelastic Phase Transition of TlH_2PO_4 Acoustic Phonon Softening
- Elastic Instability in the Ferroelastic Phase Transition of TlH_2PO_4 Studied by Brillouin Scattering
- Investigation of Grain-Size Influence on the Ferroelectric-to-Paraelectric Phase Transition in BaTiO_3 Ceramics by Means of AC Calorimetry
- Dielectric Relaxation in Ferroelectric NH_4In(SO_4)_2・12H_2O
- Dielectric Relaxation in NH_4Cr (SO_4)_2・12H_2O
- Ferroelectricity and Dielectric Relaxation in NH_4Al (SO_4)_2・12H_2O
- Dielectric Studies of Monoclinic Rb_Cs_xD_2PO_4 on the Phase Transitions
- Isotope Effect of Monoclinic Rb (D_H_x)_2PO_4 on the Phase Transitions
- New Phase Transitions of Monoclinic RbD_2PO_4 and Its Forced Ttansition to the Ferroelectric State
- 21pYP-5 Ferroelasticity and the Proton-induced Superionic Conduction : Experiment(Recent developments in and around physics of superionic conductors)
- NMR Study on Ferroelectric (CH_3)_2NH_2H_2AsO_4
- NMR Study on Ferroelectric (CH_3)_2NH_2H_2AsO_4
- Thermal and NMR Studies on Phase Transitions of Tl_2SeO_4
- Ferroelastic Phase Transitoin in Tl_2SeO_4
- Dielectric Study on the Low-Temperature Phase Transition of TlH_2 PO_4
- s-Character of MX_4(M=C,Si,Ge,X=F,Cl,Br,I) Molecules
- Surfactant-Induced Bond Strengthening in As-Grown Film Surfaces
- Dielectric Studies on the Phase Transitions of {(NH_4)_3H (SO_4)_2}_{(ND_4)_3D (SO_4)_2}_x System : Ferroelectricity in (NH_4)_3H (SO_4)_2
- Heat Capacity and Thermal Expansion of NH_3CH_2COOH・H_2PO_3(Condensed Matter : Structure, Mechanical and Thermal Properties)
- Dielectric Dispersion Studies in Pyridinium Periodate Single Crystal
- Crystal Structure of NH_3CH_2COOHH_2PO_3 in the Ferroelectric Phase
- Domain Structure and Deflection of Light at Domain Walls in RbHSeO_4
- Dielectric, Thermal and Optical Studies of Phase Transitions in TIH_2AsO_4 Single Crystal
- Dielectric Studies of NaNH_4(SO_4)_(SeO_4)_x・2H_2O on the Phase Transition
- Phase Transitions in (CH_3NH_3)_4InBr_7
- Optical and X-Ray Studies in Ferroelastic Cs_3H(SeO_4)_2
- Dielectric,Dilatometric and AC Calorimetric Studies of a New Phase Transition in (CH_3NH_3)NaSO_4・6H_2O
- Dielectric Dispersion in Ferroelectric (CH_3)_2NH_2H_2AsO_4 and Isotope Effect on the Transition Temperature
- Phase Transition in Ferroelectric (CH_3)_2NH_2H_2AsO_4 and Its Dielectric Property
- Phase Transition in (CH_3)_2NH_2H_2PO_4 and Its Ferroelectric Activity
- Hydrogen Rearrangements in CsHSeO_4 Accompanied with both the Phase Transition and Domain-Boundary-Movement
- Isotope Effect of Glycinium Phosphite NH_3CH_2COOH・H_2PO_3 Studied by Neutron Diffraction(Condensed matter: structure and mechanical and thermal properties)
- Neutron Diffraction Study of Ferrielectric Phase Transition in Monoclinic RbD_2PO_4(Condensed matter: structure and mechanical and thermal properties)
- Dielectric Study on the Effect of Hydrostatic Pressure on the Phase Transitions in the System of {(NH_4)_3H (SO_4)_2}_{(ND_4)_3D (SO_4)_2}_x
- Pressure-Temperature Phase Diagram of (ND_4)_3D (SO_4)_2
- Ferroelectricity of Deuterated Triammonium Deuterium Disulfate and Isotope Effect on Ferroelectric Activity
- Dielectric and Dilatometric Studies of Phase Transitions in (ND_4)_3D (SeO_4)_2 and Isotope Effect
- Dielectric,Elastic and Thermal Properties on a New Phase Transition in (CH_3NH_3)NaSeO_4・6H_2O
- Acoustic Phonon Softening and Spontaneous Strains in KD_3(SeO_3)_2
- Dielectric Study of Monoclinic RbD_2PO_4 in High-Temperature Phase
- High-Temperature Phase Transition in RbH_2PO_4 : Condensed Matter: Structure, etc.
- Structural Study of Partially Deuterated Glycinium Phosphite in the Paraelectric Phase
- Critical Slowing-Down and Static Dielectric Constant of Monoclinic RbD_2PO_4
- Dielectric Study of Phase Transitions in Cs_3H (SeO_4)_2 and Its Isotope Effect
- Ferroelectricity in 3C_6H_4(OH)_2.CH_3OH
- Ferroelastic Phase Transition in (NH_4)_3H (SeO_4)_2
- Ferroelectricity and Successive Phase Transitions in (NH_4)_2ZnBr_4
- Dielectric and Thermal Studies on New Phase Transitions of CsHSO_4
- Study of the Phase Transition in KH_3(SeO_3)_2. : I. Acoustic Phonon Softening
- 27pTM-11 対称性から予測されるβ-R_2(MoO_4)_3のマルチフェロイック特性III(27pTM 酸化物系,光散乱,領域10(誘電体,格子欠陥,X線・粒子線,フォノン))
- 22aGN-10 対称性から予測されるβ-R_2(MoO_4)_3のマルチフェロイック特性IV(22aGN マルチフェロイック,領域10(誘電体,格子欠陥,X線・粒子線,フォノン))
- Ferrielectricity of Monoclinic RbD_2PO_4
- Dielectric and Thermal Studies on New Phase Transition of CsHSeO_4
- 24pCL-6 対称性から予測されるβ-R_2(MoO_4)_3のマルチフェロイック特性V(24pCL 誘電体(若手奨励賞受賞記念講演,マルチフェロイック,リラクサー),領域10(誘電体,格子欠陥,X線・粒子線,フォノン))
- 19pAG-8 対称性から予測されるβ-R_2(MoO_4)_3のマルチフェロイック特性VI(誘電体(招待講演,マルチフェロイック),19pAG 領域10,領域8合同チュートリアル講演,領域10(誘電体,格子欠陥,X線・粒子線,フォノン))
- Pressure Effect on Phase Transition in Partially Deuterated Cs(H1-xDx)2PO4
- 28pXS-7 対称性から予測されるβ-R_2(MoO_4)_3のマルチフェロイック特性VII(28pXS 誘電体(マルチフェロイック,シミュレーション他),領域10(誘電体,格子欠陥,X線・粒子線,フォノン))
- Investigation of Grain-Size Influence on the Ferroelectric-to-Paraelectric Phase Transition in BaTiO3 Ceramics by Means of AC Calorimetry
- 26aKA-6 対称性から予測されるβ-R_2(MoO_4)_3のマルチフェロイック特性 VIII(誘電体・フォノン(水素結合系,TGS,シミュレーション),領域10(誘電体,格子欠陥,X線・粒子線,フォノン))