Hydrogen Rearrangements in CsHSeO_4 Accompanied with both the Phase Transition and Domain-Boundary-Movement
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概要
- 論文の詳細を見る
Hydrogen rearrangements accompanied with the movement of domain boundariesin CsHSe0. below the ferroelastic phase transitioru temperature (7'.= 128'C) andpossible motional states of hydrogens above T. were studied based on the crystal struclure obtained in the X-ray re-examination at room temperature and twinning condi-Lions for ferroelastic domains observed below T.. -the crystal was confirmed to bemonoclinic with the space group P2. / c and to have a superlattic:e structure below T.,while it is tetragonal with the space group 14. / amd above T.. It was deduced by taking account of symmetry change from P2. / c to 14. / amd and twinning conditionsthat the hydrogen bonds in CsllSeO. above T. are broken instantaneously and thehydrogens are hopping among the 16-fold (f ) equivalent positions, leading to socalled three-dimensional superionic conductivity of hydrogens above T..[Csl-ISe0., ferroelastics, crystal structure, domain structure, hydrogen bond, ll superionic conductivityl
- 社団法人日本物理学会の論文
- 1990-01-15
著者
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TANAKA MINORU
Department of Thoracic Surgery, Nagoya University School of Medicine
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KOMUKAE Masaru
Department of Applied Physics, Faculty of Science, Science University of Tokyo
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OSAKA Toshio
Department of Applied Physics, Faculty of Science, Science University of Tokyo
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Osaka T
Tokyo Univ. Sci. Tokyo
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Osaka Toshio
Department Of Applied Physics Faculty Of Science Tokyo University Of Science
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Osaka Toshio
Department Of Applied Physics Faculty Of Science Science University Of Tokyo
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Komukae M
Tokyo Univ. Sci. Tokyo
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Komukae Masaru
Department Of Applied Physics Faculty Of Science Science University Of Tokyo
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MAKITA Yasuharu
Department of Applied Physics,Faculty of Science,Science University of Tokyo
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UCHIDA Tokiko
Department of Industrial and Engineering Chemistry, Faculty of Science and Technology, Science Unive
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Kozawa K
Sci. Univ. Tokyo Chiba‐ken
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Kozawa Kozo
Department Of Industrial And Engineering Chemistry Faculty Of Science And Technology Science Univers
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Uchida T
Saga Univ. Saga
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Uchida Tokiko
Department Of Industrial And Engineering Chemistry Faculty Of Science And Technology Science Univers
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Makita Yasuharu
Department Of Applied Physics Faculty Of Science Science University Of Tokyo
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Tanaka Minoru
Department Of Thoracic Surgery Nagoya University School Of Medicine
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Tanaka Minoru
Department Of Anatomy Kyoto Prefectural University Of Medicine
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Tanaka Minoru
Department Of Applied Physics Faculty Of Science Science University Of Tokyo
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Uchida Tokiko
Department of Chemistry Faculty of Science The University of Tokyo
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