XPS Valence Band and Core Level Spectra of Sputter-Deposited Fe-Cu,Fe-Ag and Fe-Cu-Ag Alloy Films
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概要
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Valence band and core-level characteristics of sputter-deposited Fe-Cu, Fe-Ag andFe-Cu-Ag alloy films have been studied by X-ray photoelec'cron spectroscopy usingmonochromatized Al Ka radiation. These films are composed of metastable bcc, fccand amorphous phases depending on the alloy cormposition. Their valence band spec-Era consist of well-resolved peaks representative of Fe-, Cu- and Ag-derived d bandsin the respective alloy systems, whose spectral features are si?nilar to those of Ni-Cuand Pd-Ag alloys reported by Ilfifner et at. The spectral component of the Fe-derivedd band near the Fermi level tends to shrink rapidly in Cu- and Ag-rich fcc alloys. Thisfeature is discussed in relation to the variation of the Curie temperature with the Cuor Ag concentration in these alloys. The core-level spectra of Fe 2p, Cu 2p and Ag 3dstates reveal that charge transfer among constituent elements is not appreciable. Theeffects of thermal annealing and the attendant phase separation upon these XPS spec-Era are also studied.
- 社団法人日本物理学会の論文
- 1989-05-15
著者
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Nakamura Yoji
Department of mechanical and System Engineering,Ryukoku University
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Sumiyama Kenji
Department of Metal Science and Technology, Kyoto University
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TANAKA Kazuhide
Department of Metallurgy, Nagoya Institute of Technology
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Nakamura Yoji
Department Of Material Science And Technology Kyoto University
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Sumiyama Kenji
Department Of Material Science And Technology Kyoto University
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Tanaka Kazuhide
Department Metallurgical Engineering Nagoya Institute Of Technology
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Ushida Masanori
Department of Materials Science and Engineering,Nagoya Institute of Technology
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Ushida Masanori
Department Of Materials Science And Engineering Nagoya Institute Of Technology
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Tanaka Kazuhide
Department of Materials Science and Engineering,Nagoya Institute of Technology
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SUMIYAMA Kenji
Department of Frontier Materials Graduate School of Engineering, Nagoya Institute of Technology
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