A Transformation from Crystalline to Amorphous State Observed in the Ferroelectric Phase of LiH_3(SeO_3)_2

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概要

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• An unexpected reduction of the X-ray diffraction intensity was found at 80'C inthe ferroelectric phase of LiH,(Se0,).. It follows from the crystal structure analysisthat no crystal structure change takes place at 80'C. It is concluded that thisphenomenon is the irreversible transformation frorn the crystalline state to the amor-phous state. The transformation is undergone selectively from the surface with an ex-tremely long characteristic time. It is very likely that the previously reportedsuperionic character originates in this transformation.[LiH3(Se0.)., amorphous, f'erroelectrics, phase transition, superionic conduc- lj tivityl

• 1989-10-15

著者

• Nakamaura Eiji

  Faculty Of Science Hiroshima University

• MORIOKA Noboru

  Department of Forestry, Faculty of Agriculture, Nagoya University

• ITOH Kazuyuki

  Department of Biology, Osaka Medical Center for Cancer and Cardiovascular Diseases

• Nakamura Eiji

  Department Of Electrical Engineering Faculty Of Engineering Kanagawa University

• Morioka N

  Nagoya Univ. Nagoya Jpn

• MASUMURA Hisashi

  Department of M

• Itoh Kazuyuki

  Department Of Biology Osaka Medical Center For Cancer And Cardiovascular Diseases

• Itoh Kazuyuki

  Department Of M<aterials Science Faculty Of Science Hiroshima University

• Masumura Hisashi

  Department Of M<aterials Science Faculty Of Science Hiroshima University

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