Crystal Structure of Rb_2ZnCl_4 in the Modulated Phases
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概要
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The modulated crystal structures of Rb.ZnCl. are determined by using X-ray retleclion data collected by an automatic four-circle di1Tractometer. In contrast to the dis-ordered structure in the normal phase, the commensurate structure at 146 K issuccessfully determined by a harmonic vibration model with normal values of thethermal displacement of atoms. The incommensurate structure projected onto thethree-dimensional section is determined at 233 K on the basis of the main reflections.The structure thus obtained has large mean-square displacements compared with thevalues in the other phases. This result is explained by the fact that the thermaldisplacement of the projection structure includes the contribution from the staticmodulated distortion of which amount can be evaluated from the temperature changeof the mean-square atomic displacement.[Rb.ZnC]., ferroelectrics, crystal structure analysis, X-rays, incommensurate ]l structure, commensurate structurel
- 社団法人日本物理学会の論文
- 1989-06-15
著者
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Nakamura Eiji
Department Of Electrical Engineering Faculty Of Engineering Kanagawa University
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Itoh Kazuyuki
Department Of Biology Osaka Medical Center For Cancer And Cardiovascular Diseases
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HINASADA Akinori
Department of Materials Science,Faculty of Science,Hiroshima University
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DAIKI Masahiro
Department of Materials Science,Faculty of Science,Hiroshima University
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Daiki Masahiro
Department Of Materials Science Faculty Of Science Hiroshima University
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Hinasada A
Department Of Materials Science Faculty Of Science Hiroshima University
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