Theory of A.c. polarization and A.c. polarography and voltammetry of two-step surface redox reactions.
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概要
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Theoretical expressions are presented of the a.c. polarization and of the a.c. polarography and voltammetry for a two-step surface redox reaction (O<SUB>ad</SUB>+<I>n</I><SUB>1</SUB>e\rightleftharpoonsS<SUB>ad</SUB>,S<SUB>ad</SUB>+<I>n</I><SUB>2</SUB>e\rightleftharpoonsR<SUB>ad</SUB>) in which the charge transfer reactions take place exclusively between the adsorbed reactants O<SUB>ad</SUB>, S<SUB>ad</SUB>, and R<SUB>ad</SUB>, and all the reactants are adsorbed so strongly that the amount of O, S, or R brought to or removed from the electrode surface can be neglected. The interaction between the adsorbed reactants is assumed to be expressed by Frumkin's <I>a</I>-parameters. The effect of the double layer impedance is taken into account. Several simplified cases are discussed in detail.
- 公益社団法人 日本化学会の論文
著者
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Kakutani Tadaaki
Department Of Agricultural Chemistry Faculty Of Agriculture Kyoto University
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Senda Mitsugi
Department Of Agricultural Chemistry College Of Agriculture Kyoto University
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