Electrocatalytic Oxidation of Glucose at a Glucose Oxidase-Immobilized Benzoquinone Mixed Carbon Paste Electrode
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概要
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Glucose oxidase (GOD) was immobilized on the surface of a benzoquinone (BQ)-mixed carbon paste electrode (CPE) by coating the enzyme-loaded electrode surface with a nitrocellulose film. This film-coated glucose oxidase-immobilized benzoquinone-mixed carbon paste electrode (GOD-BQ-CPE) served as a biocatalyst electrode for electro-oxidation of D-glucose. The catalytic oxidation current at 0.5V vs. SCE was analyzed as a function of the concentration of D-glucose, the amount of the mixed benzoquinone in carbon paste electrode, the amount of the immobilized enzyme on the carbon paste electrode surface and the thickness of the coating film. The kinetics of the electrocatalysis at the film-coated GOD-BQ-CPE were interpreted by the concept of the enzyme reaction layer on the carbon paste electrode surface.
- 社団法人 日本農芸化学会の論文
著者
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HAMADA Hirokazu
Department of Agricultural Chemistry, Faculty of Agriculture, Kyoto University
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Ikeda Tokuji
Department Of Agricultural Chemistry Faculty Of Agriculture Kyoto University
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Senda Mitsugi
Department Of Agricultural Chemistry College Of Agriculture Kyoto University
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IKEDA Tokuji
Department oj Agricultural Chemistry, Faculty of Agriculture, Kyoto University
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