Synthesis of Allyl 3-Deoxy-D-manno-2-octulopyranosidic Acid 4- and 5-Phosphates.
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概要
- 論文の詳細を見る
Allyl glycosides (ketosides) of pyranosidic 3-deoxy-D-<I>manno</I>-2-octulosonic acid (Kdo), phosphorylated at either positions 4 or 5 were synthesized with the aim to study the biological properties of phosphorylated Kdo. The α and β-allyl glycosides prepared from a pyranosidic fluoride of diisopropylidene Kdo were protected at the 7- and 8-positions, and then <I>O</I>-phosphorylated at the 4- or 5-position by the phosphoramidite procedure. Separation of the positional isomers followed by deprotection afforded four compounds in pure states.
- 公益社団法人 日本化学会の論文
著者
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Rietschel Ernst
Forschungsinstitut Borstel
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Kusumoto Shoichi
Department Of Chemistry Faculty Of Science Osaka University
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Shiba Tetsuo
Department Of Chemistry Faculty Of Science Osaka University
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Fukase Koichi
Department of Chemistiy, Graduate School of Science, Osaka University
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Kamikawa Takashi
Department of Chemistry, Faculty of Science, Osaka University
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Iwai Yukari
Department of Chemistry, Faculty of Science, Osaka University
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