TMSCl as a Mild and Effective Source of Acidic Catalysis in Fischer Glycosidation and Use of Propargyl Glycoside for Anomeric Protection(Organic Chemistry)

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概要

• 論文の詳細を見る

• Practical Fischer glycosidation was effected at room temperature or 60℃ by using 5 to 10 equiv. of TMSCl. The anomeric propargyl group formed by this method was found to be a versatile new protecting group, being stable in neat TFA but readily cleaved by treatment with Co_2(CO)_8 and TFA in CH_2Cl_2 via the formation of an alkyne-Co complex.

• 社団法人日本農芸化学会の論文
• 2002-01-23

著者

• Fukase Koichi

  Department Of Chemistry Graduate School Of Science Osaka University

• Fukase K

  Osaka Univ. Coll. Sci. Osaka

• Fukase K

  Osaka Univ. Osaka

• Fukase Koichi

  Dep. Of Chemistry Graduate School Of Sci. Osaka Univ.

• Izumi Minoru

  Department Of Chemistry Graduate School Of Science Osaka University

• Izumi Minoru

  Department Of Bioresources Chemistry Faculty Of Agriculture Okayama University

• Fukase Koichi

  Department Of Chemistry Columbia University

• KUSUMOTO Shoichi

  Department of Chemistry, Graduate School of Science, Osaka University

• Kusumoto Shoich

  Department Of Chemistry Osaka University

• Kusumoto Shoichi

  Department Of Chemistry Graduate School Of Science Osaka University

• Kusumoto Shoichi

  Department Of Chemistry Osaka University College Of Science

• Kusumoto Shoichi

  Department Of Chemistry Faculty Of Science Osaka University

• Kusumoto S

  Department Of Chemistry Graduate School Of Science Osaka University

• Kusumoto S

  Osaka Univ. Osaka Jpn

• IZUMI Minoru

  Department of Biofunctional Chemistry, Graduate School of Natural Science and Technology, Okayama University

• Fukase Koichi

  Department of Chemistiy, Graduate School of Science, Osaka University

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