4-Azidobutyryl group for temporary protection of hydroxyl functions.
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概要
- 論文の詳細を見る
4-Azidobutyryl esters formed from hydroxyl compounds and 4-azidobutyryl chloride were shown to be cleaved via reduction to 4-aminobutyrate followed by intramolecular O→N-acyl migrations to regenerate the free hydroxyl groups. High susceptibility of azide group to reduction enables the selective removal of this acyl group leaving many other functional groups unchanged.
- 公益社団法人 日本化学会の論文
著者
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Kusumoto Shoichi
Department Of Chemistry Faculty Of Science Osaka University
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Shiba Tetsuo
Department Of Chemistry Faculty Of Science Osaka University
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Sakai Keiichiro
Department Of Obstetrics And Gynecology Hokkaido University School Of Medicine
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