Reactions of Haloferrocenes. II. Kinetic Studies of the Reaction of Haloferrocene with Copper (I) Chloride - Pyridine Complex

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概要

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• The reaction of bromoferrocene with copper(I) chloride - pyridine complex was found to be second-order, that is, first-order in each of bromoferrocene and copper(I) chloride-pyridine complex. The results obtained from the competitive reactions between bromoferrocene and bromobenzene indicated that bromoferrocene was 10<SUP>3</SUP> times more reactive than bromobenzene in the halogen-exchange reaction. The effects of the pyridine bases on the halogen-exchange reaction of bromoferrocene were examined, and the trend of the results was found to be different from that of bromobenzene. The reason for this was discussed on the basis of the reaction mechanism.

• 公益社団法人 日本化学会の論文

著者

• Motoyama Izumi

  Department Of Applied Chemistry Faculty Of Engineering Kanagawa University

• Sato Masaru

  Department Of Applied Chemistry School Of Advanced Science And Engineering Faculty Of Science And En

• Hata Kazuo

  Department of Chemistry, Faculty of Science, Tokyo Metropolitan University

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