The temperature dependence of the mixed and intervalence state in mono-oxidized trans-.MU.-(as-indacene)bis(cyclopentadienyliron).
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概要
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The temperature dependence first observed in the Mössbauer spectrum for mono-oxidized <I>trans</I>-μ-(<I>as</I>-indacene)bis(cyclopentadienyliron) was interpreted in terms of the increase in the rate of intervalence-electron transfer between two irons with an increase in the temperature. The cyclic voltammetric study of <I>trans</I>-μ-(<I>as</I>-indacene)bis(cyclopentadienyliron) indicates that the metal-metal interaction in the monocation of the compound is greater than that in the monocation of biferrocene at room temperature.
- 公益社団法人 日本化学会の論文
著者
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Motoyama Izumi
Department Of Applied Chemistry Faculty Of Engineering Kanagawa University
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Sano Hirotoshi
Deparment of Chemistry, Faculty of Science, Tokyo Metropolitan University
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