13C-CP-MAS NMR spectroscopic study of the reaction products of osmocene with Lewis acids.
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概要
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The adducts of osmocene derivatives with Lewis acids were studied by means of <SUP>13</SUP>C-CP-NMR spectroscopy and other physicochemical techniques. The large low-field shifts found through <SUP>13</SUP>C-CP-MAS NMR and <SUP>1</SUP>H NMR spectroscopy and the organotin(IV) species found in the <SUP>119</SUP>Sn-Mössbauer spectroscopic data suggest the presence of direct chemical bonds between the osmium atoms and the Lewis acids in the adducts.
- 公益社団法人 日本化学会の論文
著者
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Watanabe Masanobu
Department Of Applied Chemistry Faculty Of Engineering Kanagawa University
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Sano Hirotoshi
Deparment of Chemistry, Faculty of Science, Tokyo Metropolitan University
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