Moessbauer spectroscopic study on the mixed-valence states of 1',1'"-dimethyl-, 1',1'"-dipentyl-, 1',1'"-dihexyl-, and 1',1'"-didecylbiferrocenium triiodide.

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概要

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• 1′,1'″-Dimethyl-, 1′,1'″-dipentyl-, 1′,1'″-dihexyl-, and 1′,1'″-didecylbiferrocene were synthesized and Mössbauer spectroscopic measurements of their monocation salts were carried out at various temperatures in order to know the mixed-valence states. Effects of alkyl substituent on the valence states of iron atoms in the monocation salts of 1′,1'″-dialkylbiferrocenes are discussed.

• 公益社団法人 日本化学会の論文

著者

• NAKASHIMA Satoru

  Department of Biotechnology, University of Tokyo

• Motoyama Izumi

  Department Of Applied Chemistry Faculty Of Engineering Kanagawa University

• Katada Motomi

  Department of Chemistry, Faculty of Science, Tokyo Metropolitan University

• Sano Hirotoshi

  Deparment of Chemistry, Faculty of Science, Tokyo Metropolitan University

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