Moessbauer studies of mercury(II) salt adducts of (2)ferrocenophane derivatives.
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概要
- 論文の詳細を見る
Various adducts of mercuric salts with [2]ferrocenophane and 1,1,2,2-tetramethyl[2]ferrocenophane, were prepared by treating HgX<SUB>2</SUB> (X=Cl<SUP>−</SUP>, I<SUP>−</SUP>, CN<SUP>−</SUP>) with the [2]ferrocenophane derivatives in ether. The adducts were studied by Mössbauer spectroscopy and other physicochemical measurements. Anomalously large quad-rupole splitting values of the adducts (about 3.10–3.30 mm s<SUP>−1</SUP> at 78 K) suggest the presence of a strong direct interaction between the Fe and Hg atoms.
- 公益社団法人 日本化学会の論文
著者
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Motoyama Izumi
Department Of Applied Chemistry Faculty Of Engineering Kanagawa University
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Watanabe Masanobu
Department Of Applied Chemistry Faculty Of Engineering Kanagawa University
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Ichikawa Hajime
Department Of Cardiovascular Surgery National Cerebral And Cardiovascular Center
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Sano Hirotoshi
Deparment of Chemistry, Faculty of Science, Tokyo Metropolitan University
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Ichikawa Hajime
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
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