57Fe-Moessbauer and 13C-CP-MAS NMR spectroscpic studies of the reaction products of ferrocene dirivatives with mercury (II) salts.
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概要
- 論文の詳細を見る
The unstable adducts of ferrocene and methylferrocene and the stable adducts of biferrocene, diferrocenylmethane, 1,2-diferrocenylethane, and [<I>n</I>]ferrocenophane (<I>n</I>=2, 3) with HgX<SUB>2</SUB> (X=Cl, Br, I, and BF<SUB>4</SUB>) were studied by means of <SUP>57</SUP>Fe-Mössbauer and high-resolution solid-state <SUP>13</SUP>C NMR spectroscopies. The large quadrupole splitting (Q. S.) values in the <SUP>57</SUP>Fe-Mössbauer and the large low-field shifts in the <SUP>13</SUP>C-CP-MAS NMR, spectroscopy suggest the presence of a direct chemical bond between the Fe and Hg atoms.
- 公益社団法人 日本化学会の論文
著者
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Masuda Yuichi
Department Of Chemistry Faculty Of Science Ochanomizu University
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Motoyama Izumi
Department Of Applied Chemistry Faculty Of Engineering Kanagawa University
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Watanabe Masanobu
Department Of Applied Chemistry Faculty Of Engineering Kanagawa University
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Watanabe Masanobu
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
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Sano Hirotoshi
Deparment of Chemistry, Faculty of Science, Tokyo Metropolitan University
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