Reactions of Haloferrocenes. III. The Reaction of Haloferrocenes with Copper(I) Benzenethiolate, Thiocyanate, Acetate, and Benzoate
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概要
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Iodoferrocene reacted with copper(I) benzenethiolate in boiling pyridine to give ferrocenyl phenyl sulfide in a quantitative yield. The reaction of iodoferrocene with copper(I) thiocyanate gave diferrocenyl disulfide. The behavior of copper(I) acetate and benzoate toward haloferrocene was found to be different from those of the other copper(I) salts: the reactions in boiling pyridine gave the corresponding ferrocenyl ester, together with a small quantity of ferrocene, while the reaction in boiling toluene produced biferrocenyl as the main product. The reaction mechanism of the ferrocenyl ester and biferrocenyl formations was discussed.
- 公益社団法人 日本化学会の論文
著者
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Motoyama Izumi
Department Of Applied Chemistry Faculty Of Engineering Kanagawa University
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Sato Masaru
Department Of Applied Chemistry School Of Advanced Science And Engineering Faculty Of Science And En
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Hata Kazuo
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
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