Reactions of Haloferrocenes. IV. The Condensation of Haloferrocenes with Various Carboxylic Acids in the Presence of Copper(I) Oxide
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概要
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The condensation reaction of haloferrocenes with various carboxylic acids in the presence of copper(I) oxide was studied extensively. The reaction generally afforded the corresponding ferrocenyl carboxylates, along with a comparable amount of ferrocene. The change in the distribution of the reaction products was examined under various conditions in the reaction of bromoferrence with benzoic acid. From the discussion of the reaction mechanism, it was concluded that the ferrocenyl ester and ferrocene are produced through different active species. The reaction under proper conditions was found to be useful for the preparation of ferrocenyl esters.
- 公益社団法人 日本化学会の論文
著者
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Motoyama Izumi
Department Of Applied Chemistry Faculty Of Engineering Kanagawa University
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Sato Masaru
Department Of Applied Chemistry School Of Advanced Science And Engineering Faculty Of Science And En
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Lam Yau
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
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Hata Kazuo
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
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