Moessbauer spectroscopic studies of mercury(II) chloride adducts with binuclear metallocenes.
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概要
- 論文の詳細を見る
Biferrocene and ferrocenylruthenocene react with HgCl<SUB>2</SUB> to give very stable adducts. Large quadrupole splitting values (2.93 mm s<SUP>−1</SUP> for biferrocene–2HgCl<SUB>2</SUB> and 2.99 mm s<SUP>−1</SUP> for ferrocenylruthenocene–5HgCl<SUB>2</SUB>, both at 78 K) indicate the presence of a direct interaction between the Fe and Hg atoms. The stabilities of their adducts suggest a chelating effect between the Fe and Fe or Fe and Ru atoms in biferrocene or ferrocenylruthenocene, respectively.
- 公益社団法人 日本化学会の論文
著者
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Motoyama Izumi
Department Of Applied Chemistry Faculty Of Engineering Kanagawa University
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Watanabe Masanobu
Department Of Applied Chemistry Faculty Of Engineering Kanagawa University
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Sano Hirotoshi
Deparment of Chemistry, Faculty of Science, Tokyo Metropolitan University
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