Plastic phase of formylferrocene studied by X-ray diffraction and Moessbauer spectroscopy.
スポンサーリンク
概要
- 論文の詳細を見る
The structures of both the crystal and the plastic phases of formylferrocene have been determined to be orthorhombic by single-crystal X-ray diffraction. The structural change proposes a mechanism of the transition that postulates the translational molecular motion along the a-axis. Mössbauer spectra observed in the plastic phase show little fluctuation of the electric field gradient ascribed to the orientational disorder between x, y, and z axes of the molecule.
- 公益社団法人 日本化学会の論文
著者
-
SATO Kumiko
Department of Bacteriology, Nagoya University School of Medicine
-
Iwai Makoto
Department Of Applied Chemistry Faculty Of Engineering Chiba University
-
Konno Michiko
The Institute for Solid State Physics, The University of Tokyo
-
Sano Hirotoshi
Deparment of Chemistry, Faculty of Science, Tokyo Metropolitan University
関連論文
- Prognostic Implications of Left Ventricular Wall Motion Abnormalities Associated With Subarachnoid Hemorrhage
- Growth and Optical Characterization of Cr^YAB and Cr^YGAB Crystal for New Tunable and Self-Frequency Doubling Laser
- Combined Microsurgical and Endovascular Modalities for Complex Intracranial Aneurysms
- Electrocardiogram-Gated Computerized Tomographic Angiogram in the Detection of Aneurysm Bleb and its Post-Operative Histopathological Verification
- Management of ruptured intracranial aneurysms : Selection of appropriate treatment modality, clipping or coiling(The 25th Annual Meeting of the Japanese Congress of Neurological Surgeons)
- Results of Direct Surgery Versus Coli Embolization for Cerebral Aneurysms
- Abrupt Conversion of Mixed-Valence State in Trinuclear Iron Cyanoacetate Complex
- Synthesis and Characterization of a New μ-Alkoxodiiron(III) Complex with NO_5 Donor Set Environments
- RobA-Induced Multiple Antibiotic Resistance Largely Depends on the Activation of the AcrAB Efflux
- Synthetic Study of an Antigenic Peptide Having a Partial Sequence from Plasmodium falciparum Enolase
- Solution-Phase Synthesis and Structural Analysis of Multiple Antigenic Peptides Having Partial Sequences of Plasmodium Falciparum Enolase
- Effect of Low-Frequency Vibration Method on Growing Huntite-Borate Crystals
- Bacillus cereusの産生する血管透過性亢進物質によるマウス腸管プ-ルにおける液体貯留性〔英文〕
- Group Transfer Polymerization of Methacryl-Type Poly(2-oxazoline) Macromonomers
- Reactivity in Radical Polymerization of Poly(2 - oxazoline) Macromonomers
- Double-layered lateral meniscus
- Tolosa-Hunt Syndrome with Unusual Clinical Courses : Two Case Reports
- Effects of Organic and Inorganic Mercurials on Thyroidal Functions : Inhibition of Thyroidal Peroxidase Activity (Regular Presentations) (Proceedings of the 9th Symposium on Environmental Pollutants and Toxicology)
- Conversion of the Valence State of ^Fe Atoms Produced in ^Co-labelled[Co(pyridine)_2Ni(CN)_4]
- Crystal Growth and Optical Characterization of Rare-Earth (Re) Calcium Oxyborate ReCa_40(B0_3)_3 (Re = Y or Gd) as New Nonlinear Optical Material
- Asymmetric Recognition of Hectorite Modified with Chiral Arylethylammonium
- Chemical Modification of Hectorite by Interlayer-Polymerization of (3-Aminopropyl)trimethoxysilane
- Reactivity in the Radical Copolymerization of Poly(2 - oxazoline) Macromonomers with Methacrylate Monomers
- Research on Nursing Reform in Postwar Japan: Towards a New Nursing Education System during the Occupation GHQ
- Synthesis and Properties of Segmented Polyurethanes Having Poly(2-oxazoline) Chains
- Cerebrovascular Surgery Update
- Studies on the valence state of iron atoms in the mixed-valence binuclear ferrocenes by X-ray absorption near edge structure (XANES) and by X-ray photoelectron spectroscopy (XPS).
- Treatment and Results of Partially Thrombosed Giant Aneurysms
- Moessbauer spectroscopic study on the mixed-valence states of 1',1'"-bis(o-methylbenzyl)-, 1',1'"-bis(m-methylbenzyl)-, and 1',1'"-bis(p-methylbenzyl)biferrocenium triiodide.
- Moessbauer and ESR spectroscopic studies on the mixed-valence states of 1',1'"-bis(methylbenzyl)biferrocenium triiodides in crystalline and dispersed state.
- Moessbauer spectroscopic study on the mixed-valence states of 1',1'"-dimethyl-, 1',1'"-dipentyl-, 1',1'"-dihexyl-, and 1',1'"-didecylbiferrocenium triiodide.
- Plastic phase of formylferrocene studied by X-ray diffraction and Moessbauer spectroscopy.
- Preparation of mesoverdohemochrome IX.ALPHA. dimethyl ester and Moessbauer spectra of related porphyrins.
- Studies on the lattice dynamics in ferrocene derivatives by means of recoil-free fraction and thermal shift in Moessbauer spectra.
- Studies on the phase transition near the melting point in acetylferrocene.
- 197Au-Moessbauer spectroscopic studies of monomeric and trimeric gold(I) azolates.
- Successful Resection of Arteriovenous Malformations in Eloquent Areas Diagnosed by Surface Anatomy Scanning and Motor Evoked Potential
- 57Fe-Moessbauer spectroscopic study of ferrocenylruthenocene, (1)(1,1')ferroceno(1)(1,1')ruthenocenophane, and reaction products with some oxidizing agents.
- Theoretical interpretation of the Moessbauer parameter in (1)ferrocenophanes.
- 57Fe-Moessbauer and 13C-CP-MAS NMR spectroscpic studies of the reaction products of ferrocene dirivatives with mercury (II) salts.
- The temperature dependence of the mixed and intervalence state in mono-oxidized trans-.MU.-(as-indacene)bis(cyclopentadienyliron).
- The optical absorption spectra of ferrocene and biferrocene anions produced in the .GAMMA.-ray irradiation by the matrix-protection method.
- Moessbauer spectroscopic studies of the chemical effects associated with 57Co(electron capture)57Fe decay in tris-.BETA.-diketonatocobalt(III) compounds.
- 13C-CP-MAS NMR spectroscopic study of the reaction products of osmocene with Lewis acids.
- 197Au-Moessbauer spectroscopic studies of gold compounds.
- An explanation of the temperature dependence of the Moessbauer spectra of mixed valence biferrocenium derivatives with a (valence-state) order-disorder transition.
- Moessbauer spectroscopic studies of mercury(II) chloride adducts with binuclear metallocenes.
- Lifetimes of ortho-positronium in benzene solutions of .BETA.-diketonates of iron(III) and cobalt(III).
- The temperature dependence of the trapped and averaged-valence state in mono-oxidized dialkylbiferrocenes.
- Studies on the G(Fe3+.RAR.Fe2+)-value in the radiolysis caused by 6Li(n,.ALPHA.)T reaction in lithium tris(oxalato)ferrate(III).
- Analysis of tin corrosion products using conversion electron Moessbauer spectroscopy, transmission Moessbauer spectroscopy, and X-ray diffractrometry.
- Moessbauer studies of mercury(II) salt adducts of (2)ferrocenophane derivatives.
- Crystal Structure of the Potassium Salt of Chloranil
- Studies of matrix effects on 57Co-labelled tris(.BETA.-diketonato)cobalt(III) by means of Moessbauer spectroscopy.
- Mössbauer Spectroscopic Studies of the Oxidation State of 57Fe produced in 57Co-doped and γ-irradiated Trisacetylacetonatoiron(III)
- Mössbauer Spectroscopic Studies of Iron(II) and Iron(III) 1-Nitroso-2-naphtholate Complexes
- Crystal structure of mixed-valence compound 1',1'"-dipropylbiferrocenium triiodide with averaged-valence type irons at 298 K and with trapped-valence type irons at 110 K and thermal electron transfer process of mono-oxidized binuclear ferrocene derivative
- 119Sn-Mössbauer and 1H- and 55Mn-NMR Spectroscopic Studies of a Series of Compounds, R3−xXxSn-Mn(CO)5
- The Syntheses of R3Sn–Mn(CO)5−nLn(n=0 or 1) Compounds and Their 119Sn-Mössbauer and 1H-NMR Studies