Stereochemical Correlation between 10-Hydroperoxyoctadecadienoic Acid and 1-Octen-3-ol in Lentinula edodes and Tricholoma matsutake Mushrooms
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概要
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Linoleic acid (LA) incubated with a homogenate of Lentinula edodes or Tricholoma matsutake mushroom significantly increased the amount of (R)-1-octen-3-ol. The alcohol was identified as (S)-10-HODE with 90–87% and >99% enantiomeric excess (ee), respectively. During the incubation of LA with these homogenates in the presence of glutathione–glutathione peroxidase (GSH–GPx), which can reduce hydroperoxy fatty acids to the corresponding hydroxy acids, the formation of (R)-1-octen-3-ol was significantly inhibited, whereas the amount of 10-hydroxy-(8E,12Z)-8,12-octadecadienoic acid (10-HODE) was significantly increased. The acid was identified as (S)-10-HODE with 92–88% ee and >99% ee, respectively. The decrease in the amount of alcohol was approximately the same as the increase in amount of HODE in both mushrooms. These results indicate a stereochemical correlation between (R)-1-octen-3-ol and (S)-10-hydroperoxy-(8E,12Z)-8,12-octadecadienoic acid [(S)-10-HPODE] in both mushrooms.
- 社団法人 日本農芸化学会の論文
著者
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Akakabe Yoshihiko
Department of Biological Chemistry, Faculty of Agriculture, Yamaguchi University
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MATSUI Kenji
Department of Biological Chemistry, Faculty of Agriculture and Applied Molecular Bioscience, Graduat
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KAJIWARA Tadahiko
Department of Biological Chemistry, Faculty of Agriculture, Yamaguchi University
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Matsui K
Yamaguchi Univ. Yamaguchi Jpn
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Matsui Kenji
Dep. Of Biological Chemistry Fac. Of Agriculture And Dep. Of Applied Molecular Medicine Graduate Sch
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Matsui Kenji
Department Of Biological Chemistry Faculty Of Agriculture Yamaguchi University
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Akakabe Yoshihiko
Department Of Biological Chemistry Faculty Of Agriculture Yamaguchi University
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Kajiwara Tadahiko
Department Of Agricultural Chemistry Faculty Of Agriculture University Of Yamaguchi
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Matsui Kenji
Department Of Biological Chemistry Faculty Of Agriculture And Department Of Applied Molecular Medici
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Matsui Kenji
Department Of Biological Chemistry Faculty Of Agriculture And Applied Molecular Bioscience Graduate
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