Stereoselective Synthesis of Ectocarpene and Its Antipode via Microbiological Asymmetric Hydrolysis
スポンサーリンク
概要
- 論文の詳細を見る
Biological asymmetric hydrolysis of ethyl (±)-cycloheptadienecarboxylate with Rhodotorula minuta var. texensis IFO 1102 and chemical resolution of the corresponding carboxylic acid with (-)-quinine provided (R)-(+)-ethyl 2, 5-cycloheptadienecarboxylate (78% e.e.) and (S)-(+)-2, 5-cycloheptadienecarboxylic acid (95% e.e.), respectively. The (R)-(+)-carboxylate was converted to (R)-(-)-2, 5-cycloheptadienylcarbaldehyde and the (S)-(+)-carboxylic acid to (S)-(+)-2, 5-cycloheptadienylcarbaldehyde. Ectocarpene (78% e.e.), male-gamete attractant of marine brown alga, and its antipode (95% e.e.) were synthesized by stereoselective Wittig reaction between the (R)-(-)- and (S)-(+)-aldehydes and propyltriphenylphosphonium bromide in a liquid-solid two phase system using 18-crownether-t-BuOK, respectively.
- 社団法人 日本農芸化学会の論文
著者
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Hatanaka Akikazu
Department Of Agricultural Chemistry Faculty Of Agriculture University Of Yamaguchi
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Kajiwara Tadahiko
Department Of Agricultural Chemistry Faculty Of Agriculture University Of Yamaguchi
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HATANAKA Akikazu
Department of Agricultural Chemistry, University of Yamaguchi
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SASAKI Yasushi
Department of Agricultural Chemistry, University of Yamaguchi
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KIMURA Fumio
Central Research Laboratory, Ube Industries
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KAJIWARA Tadahiko
Department of Agricultural Chemistry, University of Yamaguchi
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