An Efficient Conversion of Carboxylic Acids to One-Carbon Degraded Aldehydes via 2-Hydroperoxy Acids
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概要
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After the formation of dianions of a carboxylic acid with lithium diisopropylamide, oxygen was bubbled into the solution to produce 2-hydroperoxy acid. Then the reaction mixture was acidified with a 2 N HCl solution and subsequently elevated to 50 °C to afford the aldehyde with the loss of one carbon atom. Even saturated (C10–C20) and unsaturated (C18:1) carboxylic acids were converted into the odd aldehydes (C9–C19, C17:1) in high yields. This conversion was found to be an efficient method for the preparation of carboxylic acids (Cn) to one-carbon degraded aldehydes (Cn-1) via 2-hydroperoxy acids.
- 社団法人 日本農芸化学会の論文
- 2007-05-23
著者
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Akakabe Yoshihiko
Department Of Biological Chemistry Faculty Of Agriculture Yamaguchi University
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NYUUGAKU Takeshi
Department of Biological Chemistry, Faculty of Agriculture, Yamaguchi University
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Nyuugaku Takeshi
Department Of Biological Chemistry Faculty Of Agriculture Yamaguchi University
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