SWEET AND BITTER GLYCOSIDES OF THE CHINESE PLANT DRUG, BAI-YUN-SHEN (ROOTS OF SALVIA DIGITALOIDES)
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概要
- 論文の詳細を見る
From a Chinese plant drug, Bai-Yun-Shen (roots of Salvia digitaloides), a new sweet glycoside named baiyunoside (1) was isolated. The structure of the acid-unstable aglycone of 1 named baiyunol (2) was elucidated by MS and NMR spectroscopy especially by comparison with the ^<13>C chemical shifts of β-onocerin (3). The structure of 1 was determined to be β-D-xylopyranosyl (1→2)-β-D-glucopyranoside of 2 by MS and NMR spectroscopy. Besides this sweet principle (1), several bitter iridoid glucosides were also isolated from this plant. Two of these glucosides were identified as shanzhiside methyl ester (13) and its 8-O-acetate (=acetylbarlerin, 10), respectively. A new glucoside (9) was formulated as 6-O-syringyl-8-O-acetyl shanzhiside methyl ester by the correlation with 13.
- 公益社団法人日本薬学会の論文
- 1983-02-25
著者
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周 俊
Kunming Institute of Botany, the Chinese Academy of Science
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田中 治
Institute of Pharmaceutical Sciences, Hiroshima University, School of Medicine
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周 俊
Kunming Institute Of Botany The Chinese Academy Of Science
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上田 博之
Showa College of Pharmaceutical Sciences
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林 中文
Kunming Institute Of Botany Academia Sinica
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田中 崇嗣
Lead Optimization Research Laboratory, Tanabe Seiyaku Co., Ltd.,
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田中 崇嗣
Lead Optimization Research Laboratory Tanabe Seiyaku Co. Ltd.
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田中 治
Institute Of Pharmaceutical Sciences Hiroshima University School Of Medicine
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上田 博之
Showa Coll. Pharmaceutical Sci. Tokyo Jpn
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