Triphenylphosphonium Allylide類と塩基との反応

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概要

• 論文の詳細を見る

• The reaction of 3,3-diacetyl-1-acyltriphenylphosphonium allylides (4) with bases gave 5-substituted 2-acetyl-4-triphenylphosphoniophoniophenolates (5) and 5-substituted 4-acetyl-2-triphenylphosphoniophenolates (6). These structures were established by chemical and ultraviolet spectral methods. On the other hand, deacetylation occurred by the treatment of 4 with 10% hydrochloric acid to give 3-acetyl-1-acyltriphenylphosphonium allylides (18). 3,3-Diacetyl-1-benzoyltriphenylpuhsphonium allylide (4a) was pyrolyzed to 1,1-diacetyl-4-phenylbutenyne (17).

• 公益社団法人日本薬学会の論文
• 1978-04-25

著者

• 木下 敏夫

  School of Pharmaceutical Sciences, Nagasaki University

• 渡辺 三明

  Center For Instrumental Analysis Nagasaki University

• 木下 敏夫

  長崎大学薬学部

• 木下 敏夫

  School Of Pharmaceutical Sciences Nagasaki University

• 古川 淳

  長崎大学薬学部

• 渡辺 三明

  長崎大学薬学部

• 菅原 正典

  長崎大学薬学部

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