Stable Sulfur Ylides. X. : Reactions of Carbonyl-Stabilized Sulfonium Ylides with Acetyl Chloride

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概要

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• Highly stabilized sulfonium diacethylides (1a-c) reacted with acetyl chloride to give a mixture of the enol acetates (2a-c) and the enol diacetates (3a-c). Similarly, sulfonium acetylcarbomethoxymethylides (5a, b) gave the enol acetates (6a, b). These enol acetates were hydropyzed with HCl-MeOH to give 3-methylthio- (3-phenylthio-)2,4-pentanediones (4a, b) or methyl 2-methylthio- (2-phenylthio-)acetoacetates (7a, b).

• 公益社団法人日本薬学会の論文
• 1990-01-25

著者

• 五十嵐 順悦

  Faculty of Pharmaceutical Sciences, Nagasaki University

• 木下 敏夫

  Faculty of Pharmaceutical Sciences, Nagasaki University

• 古川 淳

  Faculty of Pharmaceutical Sciences, Nagasaki University

• 古川 淳

  School Of Pharmaceutical Sciences Nagasaki University

• 五十嵐 順悦

  Faculty Of Pharmaceutical Sciences Nagasaki University

• 渡辺 三明

  Faculty of Pharmaceutical Sciences

• 木下 敏夫

  School of Pharmaceutical Sciences, Nagasaki University

• 渡辺 三明

  Center For Instrumental Analysis Nagasaki University

• 木下 敏夫

  School Of Pharmaceutical Sciences Nagasaki University

関連論文

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