芳香環の “Directed Metalation” 反応を利用した有機合成
スポンサーリンク
概要
- 論文の詳細を見る
Directed metalation has recently been recognized as an efficient new synthetic methodology for the regiospecific construction of highly substituted aromatic systems. In this review, the utility of the directed metalation strategy for the synthesis of a variety of complex aromatic compounds, especially natural products, is described.
- 社団法人 有機合成化学協会の論文
著者
関連論文
- An Efficient Synthesis of Phthalides by Diels-Alder Reaction of Sulfur-Substituted Furanones with Silyloxydienes : A Formal Synthesis of Mycophenolic Acid
- An Efficient Synthesis of 2(5H)-Furanone and Furan Derivatives Using 3-(Phenylthio)propenal as a 1,3-Dipolar Synthon
- A Regioselective Lithiation of ortho-Cresols Using the Bis(dimethylamino)phosphoryl Group as a Directing Group : General Synthesis of 2,3-Dihydrobenzo[b]furans Including Naturally Occurring Neolignans
- A Short and Convergent Synthesis of the Phytoalexins Vignafuran, 6-Demethylvigafuran, and Moracin M via Directed Lithiation Reaction
- A Facile Synthesis of Benzo[b]furan Derivatives Including Naturally Occurring Neolignans via Regioselective Lithiation of ortho-Cresols Using the Bis(dimethylamino)phosphoryl Group as a Directing Group
- The Directed ortho-Lithiation of Aryl Tetramethylphosphorodiamidates
- Reactions of Lithiated ortho-Toluamides and Related Compounds with Vinylsilanes : Syntheses of 1-Tetralones and 1-Naphthols
- Stable Sulfur Ylides. X. : Reactions of Carbonyl-Stabilized Sulfonium Ylides with Acetyl Chloride
- Stable Sulfur Ylides. XI. : Facile Preparation of Silyloxydienes from Stable Sulfur Ylides
- LITHIATION OF ORTHO-TOLYL TETRAMETHYLPHOSPHORODIAMIDATES : A FACILE SYNTHESIS OF 2-ARYLBENZOFURANS INCLUDING NEOLIGNAN, CARINATIN
- ORTHO-LITHIATION OF PHENOLS USING THE BIS(DIMETHYLAMINO)PHOSPHORYL GROUP AS A DIRECTING GROUP
- Total Synthesis of the Antibiotic WS-5995A Using a Key Reaction of o-Toluamide Anions with Homophthalic Anhydrides
- Regioselective Syntheses of Substituted Thioxanthen- and Selenoxanthen-9-one Derivatives
- 安定イオウイリドの研究(第9報)Dimethylsulfonium AcetylcarbamoylmethylideとIsoquinoline 2-Oxideとの反応
- Stable Sulfur Ylides. VIII. The Reactions of 1,3-Oxazin-4-one Derivatives
- Stable Sulfur Ylides. VII. The Reaction of Dimethylsulfonium Acetylcarbamoylmethylide with Quinoline 1-Oxide
- Triphenylphosphonium Allylide類と塩基との反応
- 安定イオウイリドの研究(第6報)Dimethylsulfonium AcetylmethoxycarbonylmethylideおよびDimethylsulfonium DiacetylmethylideとIsoquinoline 2-Oxideとの反応
- Stable Sulfur Ylides. V. Syntheses of α-Acylfuran Derivatives by Thermal and Photochemical Reaction of Allylides
- Stable Sulfur Ylides. IV. Reaction of Dimethylsulfonium Acetylmethoxycarbonylmethylide and Dimethylsulfonium Diacetylmethylide with Quinoline 1-Oxide
- Stable Sulfur Ylides. III. Reaction of Stable Sulfonium Allylides and Oxosulfonium Allylides with Alkoxides
- Stable Sulfur Ylides. II. : Syntheses of Stable Sulfonium Allylides and Oxosulfonium Allylides
- Directed Lithiation反応を利用するAnthraquinone類の合成
- An Annulation Reaction to Naphthalene-1,4-diols Using Dimethyl Phthalide-3-phosphonates
- Reaction of Lithiated Senecioamide and Related Compounds with Benzynes : Efficient Syntheses of Naphthols and Naphthoquinones
- 長所をのばし定着化を(ポスターセッションの問題点を探ぐる)
- ACRIDONES FROM THE REACTION OF N-LITHIO ANTHRANILATES WITH BENZYNES. A SHORT SYNTHESIS OF ACRONYCINE
- A Regiospecific Synthesis of Anthracyclinones Using Directed Metalation
- 「1次文献」重視で主体性の確立を(情報洪水にいかに対処するか)
- 芳香環の “Directed Metalation” 反応を利用した有機合成
- 安定イオウイリドの研究(第1報)Dimethyloxo-およびDimethylsulfonium BenzoylmethylideとAromatic Amine N-Oxide類との反応
- Benzofuro[2,3-c]pyridazine誘導体の合成
- Thianaphtheno[2,3-c]pyridazine誘導体の合成