2′-Bromomethyl-2-biphenylcarbaldehydeとシアン化ナトリウムとの反応

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概要

• 論文の詳細を見る

• The reaction of 2'-bromomethyl-2-biphenylcarbaldehyde (V) with sodium cyanide was carried out under different conditions. The reaction in a polar protic or aprotic solvent at a low temperature (-60°) gave 5-cyano-5,7-dihydrodibenz[c, e]oxepin (VI), in an aprotic solvent at room temperature it gave VI and 9-cyanophenanthrene (IX), and in an aprotic solvent at high temperature (55-65°), it gave VI, IX, and diphenide (II). The diphenide was found to be formed by autoxidation of VI. Mechanisms are proposed for the formation of VI, IX, and II.

• 公益社団法人日本薬学会の論文
• 1975-12-25

著者

• 小林 茂

  Faculty Of Home Economics Shikoku University

• 木原 勝

  徳島大学薬学部

• 木原 勝

  Faculty Of Pharmaceutical Sciences The University Of Tokushima

• 小林 茂

  徳島大学薬学部

• 橋本 敏弘

  徳島大学薬学部

• 北村 皖司

  徳島大学薬学部

• 橋本 敏弘

  徳島文理大学薬学部

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