フランとベンズアルデヒドの光付加反応
スポンサーリンク
概要
- 論文の詳細を見る
Paterno-Buchi reaction of furan and benzaldehyde was studied. Four 2 : 1 adducts were isolated and their structures were solved by chemical conversion, spectral resolution, and X-ray analysis. Two of them (B and C) has 4,6,8-trioxatricyclo [5.2.0.0^<2,5>] nonane skelton and the other (D and E) had 3,6,8-trioxatricyclo [5.2.0.0^<2,5>] nonane skelton. The former gave dimethoxy derivatives (F and G) and the latter gave mono methoxy one (H and J) by the treatment with acetic acid in methanol. Since C was presumed to be a novel sym-4,6,8-trioxatricyclo [5.2.0.0^<2,5>] nonane skelton, it was solved by X-ray analysis.
- 公益社団法人日本薬学会の論文
- 1985-01-25
著者
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三橋 進
東京薬科大学:(現)東菱薬品工業(株)大森研究所
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松本 一
Tokyo College Of Pharmacy
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飯高 洋一
東京大学薬学部
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糸川 秀治
東京薬科大学 薬学部
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飯高 洋一
西東京大・理工
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三橋 進
Tokyo College of Pharmacy
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松本 一
東京薬科大学
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大島 俊幸
東京薬科大学
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山村 裕子
東京薬科大学
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田崎 敏夫
東京薬科大学
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大島 俊幸
Research Center Taisho Parmaceutical Co. Ltd.
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大島 俊幸
大正製薬株式会社
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糸川 秀治
東京薬科大学
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