Acid-catalyzed Rearrangement of Hinesol and Related Compounds to Eudesmane Derivatives
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概要
- 論文の詳細を見る
Acid-catalyzed rearrangement of hinesol α-epoxide (5a) gave 1α-hydroxyeudesmols (9,10,11) together with other spirane-type products (6,8,14). The same reaction of α-and β-epoxides of hinesol acetate also provided eudesmane derivatives. These results and mechanistic considerations led us to re-examine the formic acid dehydration reaction of hinesol and it was found that the main product does not have the structure 3 or 4 as assumed by Marshall et al., but is identical with (+)-δ-selinene (21).
- 公益社団法人日本薬学会の論文
- 1983-06-25
著者
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三橋 進
東京薬科大学:(現)東菱薬品工業(株)大森研究所
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糸川 秀治
Tokyo College Of Pharmacy
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糸川 秀治
東京薬科大学 薬学部
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三橋 進
Tokyo College of Pharmacy
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中西 博
Tokyo College of Pharmacy
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