Structures of Amides from Asiasarum heterotropoides MAEK. var. mandshuricum MAEK.
スポンサーリンク
概要
- 論文の詳細を見る
The structures of three unstable amides from the roots of Asiasarum heterotropoides MAEK. var. mandshuricum MAEK. (Aristolochiaceae) were established as (2E, 4E)-N-isobutyl-2,4-decadienamide (pellitorine), (2E, 4E, 8Z, 10E)-N-isobutyl-2,4,8,10-dodecatetraenamide and (2E, 4E, 8Z, 10Z)-N-isobutyl-2,4,8,10-dodecatetraenamide by spectroscopic investigation and chemical transformation studies. (2E, 4E, 8Z, 10E)-N-Isobutyl-2,4,8,10-dodecatetraenamide and (2E, 4E, 8Z, 10Z)-N-isobutyl-2,4,8,10-dodecatetraenamide were identical in their chromatographic properties, but they could be identified in a mixture of both compounds by our carbon-13 nuclear magnetic resonance method, by observing the cis double bond shielding effect in comparison with the all-trans isomer.
- 公益社団法人日本薬学会の論文
- 1981-02-25
著者
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糸川 秀治
Tokyo College Of Pharmacy
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安田 一郎
東京都健康安全研究センター
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安田 一郎
東京都健康安全研究センター 医薬品部医薬品研究科
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糸川 秀治
東京薬科大学 薬学部
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安田 一郎
Tokyo Metropolitan Research Laboratory of Public Health
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安田 一郎
東京都衛研
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