Reductive Cleavage Reaction of N, N'-, N, O- and N, S-Linked Alkylidene Compounds by Sodium Borohydride
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概要
- 論文の詳細を見る
Sodium borohydride reduction was undertaken with a variety of N, N'-, N, O- and N, S-linked alkylidene compounds in aqueous ethanolic medium at room temperature. It has been realized that reductive cleavage of one of these two alkylidene carbon-heteroatom bonds is generally effected in this reduction, disclosing which alkylidene bond is initially cleaved when the two bonds are different.
- 社団法人日本薬学会の論文
- 1974-06-25
著者
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関屋 実
School Of Pharmaceutical Sciences University Of Shizuoka
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伊藤 敬一
Hokkaido College Of Pharmacy
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関屋 実
Shizuoka College of Pharmacy
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伊藤 敬一
Shizuoka College of Pharmacy
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清水 邦昭
Shizuoka College of Pharmacy
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Ito Keiichi
Hokkaido College Of Pharmacy
関連論文
- Cyclization of α- and β-Alkylthio-Substituted Amines Possessing Positively Charged Carbon at the Nitrogen. A New Synthetic Method for Thiazolidines, Thiomorpholines and Dihydro-1,4-benzothiazines
- Reactions of 2,2-Dichlorovinyl and 2,2-Dichlorovinylidene Sulfides with Butyllithium
- Thermal Rearrangements of Allyl 2,2-Dichloro-, 1,2-Dichloro- and 1,2,2-Trichloro-substituted Vinyl Sulfides
- Novel Rearrangements of α-N-Alkylamido-substituted Sulfides and Sulfones
- Syntheses and Reactions of Phenylthio-and Propylthioacetylenic Compounds
- Enantioface-Differentiating Epoxidation of Alkylidenemalononitriles with Molecular Oxygen, catalyzed by Chiral Tertiary Amines
- Formic Acid Reduction. XXVIII. Kinetic Studies on the Formic Acid Reduction of 1,1'-Benzylidenedipiperidine
- A New Insertion Reaction of Diazoalkanes with Dialkylaminomethyl Esters of Dialkyldithiocarbamic Acid and of Ethylxanthic Acid
- Chlorinolyses of Alkyl (or Aryl) Phthalimidomethyl Sulfoxides with Sulfuryl Chloride, Chlorine and Thionyl Chloride
- Nucleophilic Substitution of Alkyl (or Aryl) Imidomethyl Sulfones. A New Convenient Synthesis of Alkane (or Arene) sulfinates
- Decarboxylation Reaction. VIII. Reaction of Electron-deficient Carbon-Carbon Double Bonds with Trichloroacetic Acid. A Unique 1,1-Dichlorocyclopropane Formation through β-Trichloromethylation
- Formic Acid Reduction. XXVI. α, β-Reduction of Conjugated Nitriles with Formic Acid
- Decarboxylation Reactions. V. Reaction of N-Benzylideneanilines with Propiolic Acid
- Formic Acid Reduction. XXIV. Path of the Reductive Fission of the Centered β-Carbon Bond of Alkylidenebisketones
- Formic Acid Reduction. XXIII. Kinetic Studies on the Formic Acid Reduction of Carbon-Carbon Double Bond Adjacent to Carbonyl
- Formic Acid Reduction. XXII. Reaction of α, N-Diphenylnitrone with Formic Acid
- Formic Acid Reduction. XXI. Reductive Cleavage Reaction of p-Dimethylamino-substituted Triphenylmethanes induced by Formate
- Formic Acid Reduction. XX. Reduction of 2-Benzylidene-1,3-indandiones
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- Thermal and Photochemical Behaviors of N-[(N-Nitrosobenzylamino)-methyl] benzamide in Acidic Media
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- Chemical Behaviors of 1,1'-Diacetyl-1,1', 4,4'-tetrahydro-4,4'-bipyridine toward Organic Hydrogen Acceptors
- A New Convenient Synthesis of Diazoalkanes from N-[(N-Nitrosoalkylamino) methyl] benzamides
- Decarboxylation Reactions. III. Reaction of N, N'- and N, O-Linked Methylene Compounds with Carboxylic Acids
- Reaction of N-(Alkoxymethyl) dialkylamines and N, N'-Methylene-bisdialkylamines with Isocyanides
- Reductive Cleavage Reaction of N, N'-, N, O- and N, S-Linked Alkylidene Compounds by Sodium Borohydride
- On Behaviors of N-(Dialkylaminomethyl) imides and-amides toward Nucleophiles
- Reaction of N-(Dialkylaminomethyl) amides and N-(α-Dialkylaminobenzyl) amides with Sulfides and Cyanide
- Formic Acid Reduction. XV. Reaction of N-Methyl and N-Formyl Derivatives of p-Phenylenediamine with Formates. N-Methylation of Formanilides
- Formic Acid Reduction. XIII. Formate Reaction of the Compounds possessing the Carbon Bound to Both Oxygen and Nitrogen
- Catalytic Hydrogenation of Tetrahydro-4H-1,3-oxazin-4-ones and 4-Oxazolidinones
- Catalytic Hydrogenolyses of Benzylidene Compounds Bound to Two Oxygens, Two Nitrogens and Both Oxygen and Nitrogen
- バルビツール酸およびその誘導体のジアゾメタンによるメチル化
- Catalytic Hydrogenation of Hydroamide in the Presence of Ammonia and of Butylamine
- Studies on Stable Diazoalkanes as Potential Fluorogenic Reagents. III. : 4-Diazomethyl-2(1H)-quinolinones(Organic,Chemical)
- Studies on Stable Diazoalkanes as Potential Fluorogenic Reagents. II. : Ring-Fused 4-Diazomethylcoumarins
- On the Spectral Properties of Some Fused 4-Methylcoumarins
- A Convenient Synthesis of N-Benzyloxy-β-lactams via N-Benzyloxyimines
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- A New Method for the Introduction of Arylthio Groups at the α-Position of Alicyclic Amines
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- 1,3-DIPOLAR CYCLOADDITION LEADING TO N-ALKYLPYRROLIDINES
- 二官能性炭素の反応およびその合成化学への利用
- オクテット
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- A New Route to 4-Unsubstituted β-Lactams through Ureidomethylation of Ketene Silyl Acetals
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- One Step Syntheses of Hypoxanthines from 2-Cyano-2-phenylazoacetamides
- Facile Syntheses of Xanthines from Uric Acids
- Monobromination of Cyanoacetamides and Amidinoacetamide with Molecular Bromine
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- Reaction of Amide Homologs. XIX. Thermal Reactions of Azomethines with Formates and Formamide
- Reaction of Amide Homologs. XVIII. Catalytic Hydrogenation of N-Arylmethylene-1-acylamino-1-arylmethylamines and Hydroamides in the Presence of Formamide and Related Studies
- Reaction of N-(Butoxymethyl) dialkylamines and N, N'-Methylenebis-(dialkylamine)s with N-(1-Cyclohexen-1-yl) dialkylamines
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- Reaction of N, N-Dialkylaminomethyl Arenesulfonates with Diazoalkanes
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- Decarboxylation Reactions. VI. Reaction of α-Arylmethyleneamino-substituted Derivatives of Pyridine, Quinoline, and Isoquinoline with Trichloroacetic Anhydride
- Reactions of α-Alkyl- and α-Aryl-substituted N-Benzylideneamines with Trihaloacetylating Agents
- Reaction of Schiff Bases with Trichloroacetyl Chloride in the Presence of Triphenylphosphine
- Decarboxylation Reactions. IV. Reaction of Schiff Bases with Trichloroacetic Anhydride
- Reaction of 1-Pyrrolidino-1-cyclohexene with Imidoyl Chlorides and a Route to Producing Phenanthridines
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- Vapor-Liquid Equilibrium for Formic Acid-Triethylamine System Examined by the Use of a Modified Still. Formic Acid-Trialkylamine Azeotropes
- Paper Chromatographic Detection of Nitrogen Mustard
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- Reaction of Amide Homologs. XII. Reaction of N-Arylmethylene-1-acylamino-1-arylmethylamine with Active Methylene Compound.
- Reaction of Amide Homologs. XXI. N-Monomethylation of Aromatic Primary Amines. A Method through the Formation of N-Succinimidomethyl Compound.
- ギ酸による還元反応(第2報) : 含窒素芳香環化合物の還元
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- 鵜飼貞二先生を悼む
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- Reactions of 1-Trichloromethyl-substituted Amines with Potassium tert-Butoxide
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- Formic Acid Reduction. XXVII. Selective Reduction of Carbon-Carbon Double Bonds conjugated with Nitro and Sulfonyl Groups
- 「速報をどう考える」のパネルを読んで : その2
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- Decarboxylation Reactions. II. Reaction of Conjugated Unsaturated Ketones and Nitriles with Carboxylic Acids
- トリクロロ酢酸イオンの脱酸素を含むトリクロロ酢酸およびその無水物の反応
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- Synthesis of N-(Alkylaminomethyl) amides