Enantioface-Differentiating Epoxidation of Alkylidenemalononitriles with Molecular Oxygen, catalyzed by Chiral Tertiary Amines
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概要
- 論文の詳細を見る
The present paper describes the enantioface-differentiaing epoxidation of alkylidenemalononitriles with molecular oxygen, catalyzed by chiral tertiary amines. In the light of the by-product formation, the reaction path was concluded to involve intermolecular nucleophilic attack of a hydroperoxide intermediate catalyzed by a chiral tertiary amine. A similar epoxidation was demonstrated with cumylhydroperoxide in the presence of nicotine.
- 社団法人日本薬学会の論文
- 1981-02-25
著者
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関屋 実
School Of Pharmaceutical Sciences University Of Shizuoka
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鈴木 邦夫
School Of Pharmaceutical Sciences University Of Shizuoka
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鈴木 邦夫
Shizuoka College of Pharmacy
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関屋 実
Shizuoka College of Pharmacy
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南條 勝美
Shizuoka College of Pharmacy
関連論文
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