Formic Acid Reduction. VII. Reduction of Carbon-Carbon Double Bonds adjacent to Carbonyls
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概要
- 論文の詳細を見る
Triethylammonium formate, TEAF given by 5HCOOH・2N (C_2H_5)_3 has been introduced as a reagent effective for reduction of carbon-carbon double bond adjacent to carbonyl group, preferably double bond of central methylene carbon of 1,3-diketone. The reduction is selective at the carbon-carbon double bond. Nitro group, carbonyl group and other carbon-carbon double bond such as cinnamyl of substrate are not affected by the reduction. An improvement in the preparation of substrate compounds, α, β-unsaturated ketones, using boron trioxide as a dehydrating agent, is also given.
- 公益社団法人日本薬学会の論文
- 1970-08-25
著者
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鈴木 邦夫
School Of Pharmaceutical Sciences University Of Shizuoka
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鈴木 邦夫
Shizuoka College of Pharmacy
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関谷 実
Shizuoka College of Pharmacy
関連論文
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- Thermal Rearrangements of Allyl 2,2-Dichloro-, 1,2-Dichloro- and 1,2,2-Trichloro-substituted Vinyl Sulfides
- Novel Rearrangements of α-N-Alkylamido-substituted Sulfides and Sulfones
- Syntheses and Reactions of Phenylthio-and Propylthioacetylenic Compounds
- Enantioface-Differentiating Epoxidation of Alkylidenemalononitriles with Molecular Oxygen, catalyzed by Chiral Tertiary Amines
- Formic Acid Reduction. XXVIII. Kinetic Studies on the Formic Acid Reduction of 1,1'-Benzylidenedipiperidine
- A New Insertion Reaction of Diazoalkanes with Dialkylaminomethyl Esters of Dialkyldithiocarbamic Acid and of Ethylxanthic Acid
- Chlorinolyses of Alkyl (or Aryl) Phthalimidomethyl Sulfoxides with Sulfuryl Chloride, Chlorine and Thionyl Chloride
- Nucleophilic Substitution of Alkyl (or Aryl) Imidomethyl Sulfones. A New Convenient Synthesis of Alkane (or Arene) sulfinates
- Decarboxylation Reaction. VIII. Reaction of Electron-deficient Carbon-Carbon Double Bonds with Trichloroacetic Acid. A Unique 1,1-Dichlorocyclopropane Formation through β-Trichloromethylation
- Formic Acid Reduction. XXVI. α, β-Reduction of Conjugated Nitriles with Formic Acid
- Decarboxylation Reactions. V. Reaction of N-Benzylideneanilines with Propiolic Acid
- Formic Acid Reduction. XXIV. Path of the Reductive Fission of the Centered β-Carbon Bond of Alkylidenebisketones
- Formic Acid Reduction. XXIII. Kinetic Studies on the Formic Acid Reduction of Carbon-Carbon Double Bond Adjacent to Carbonyl
- Formic Acid Reduction. XXII. Reaction of α, N-Diphenylnitrone with Formic Acid
- Formic Acid Reduction. XXI. Reductive Cleavage Reaction of p-Dimethylamino-substituted Triphenylmethanes induced by Formate
- Formic Acid Reduction. XX. Reduction of 2-Benzylidene-1,3-indandiones
- Formic Acid Reduction. XIX. Formic Acid Reduction of 4-Dialkylaminosubstituted Nitro-, Nitroso-, Azoxy-and Azobenzenes
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- Formic Acid Reduction. XV. Reaction of N-Methyl and N-Formyl Derivatives of p-Phenylenediamine with Formates. N-Methylation of Formanilides
- Formic Acid Reduction. XXVIII. Kinetic Studies on the Formic Acid Reduction of 1,1'-Benzylidenedipiperidine
- Formic Acid Reduction. XXVIII. Kinetic Studies on the Formic Acid Reduction of 1,1'-Benzylidenedipiperidine
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- Decarboxylation Reactions. I. Reaction of Enamines with Carboxylic Acids
- Formic Acid Reduction. XII. Reductive Fission of Bridged Carbon-Carbon Bond of α, α'-Benzylidene- and α, α'-Methylene-bisketones
- Formic Acid Reduction. X. Reductive Fission of Bridged Carbon-Carbon Bond of Bisdimedone Derivatives
- Formic Acid Reduction. IX. Reactions of 5,5-Dimethyl-1,3-cyclohexanedione with TEAF and Their Reaction Routes
- Formic Acid Reduction. VII. Reduction of Carbon-Carbon Double Bonds adjacent to Carbonyls
- Trimethylsilyl Triflate-Catalyzed 1,3-Dipolar Cycloaddition Leading to N-Unsubstituted Pyrrolidines