Intramolecular Aldol Condensations of the Reaction Products formed from 2,4-Pentanedione and Aldehydes
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概要
- 論文の詳細を見る
The aldol condensation products, 5-alkyl-4,6-diacetyl-3-hydroxy-3-methylcyclohexanone (R=H, CH_3,C_6H_5) and 3,5-diacetyl-2,6-heptanedione formed from 2,4-pentanedione and aldehydes underwent further reactions involving aldol condensations and dehydrations on heating with the liquid formate, TEAF, given by 5HCO_2H・2NEt_3. These reactions finally gave the two isomers of dimethylbicyclo [3.3.1] nonadienediones. In the case of the formaldehyde condensation products, formate reactions giving 4,6-diacetyl-3-methylcyclohex-2-en-1-one and 2,4-diacetyl-5-methylphenol were also realized.
- 公益社団法人日本薬学会の論文
- 1973-06-25
著者
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関屋 実
School Of Pharmaceutical Sciences University Of Shizuoka
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鈴木 邦夫
School Of Pharmaceutical Sciences University Of Shizuoka
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鈴木 邦夫
Shizuoka College of Pharmacy
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関屋 実
Shizuoka College of Pharmacy
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森本 俊明
Shizuoka College of Pharmacy
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