N-Alkylamidomethylation at Electron-rich Carbons in the 1,3,5-Trialkylhexahydro-1,3,5-triazine-Acetyl Chloride System
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概要
- 論文の詳細を見る
A new N-alkylamidomethylation reaction at electron-rich carbons has been developed using 1,3,5-trialkylhexahydro-1,3,5-triazine in the presence of acetyl chloride. This reaction was carried out not only with aromatics such as phenols, alkoxybenzenes and aromatic amines, but also olefins such as styrene and vinyl ethers.
- 社団法人日本薬学会の論文
- 1980-04-25
著者
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関屋 実
School Of Pharmaceutical Sciences University Of Shizuoka
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関屋 実
Shizuoka College of Pharmacy
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森本 俊明
Shizuoka College of Pharmacy
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池田 潔
Shizuoka College Of Pharmacy
関連論文
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- Reactions of 2,2-Dichlorovinyl and 2,2-Dichlorovinylidene Sulfides with Butyllithium
- Thermal Rearrangements of Allyl 2,2-Dichloro-, 1,2-Dichloro- and 1,2,2-Trichloro-substituted Vinyl Sulfides
- Novel Rearrangements of α-N-Alkylamido-substituted Sulfides and Sulfones
- Syntheses and Reactions of Phenylthio-and Propylthioacetylenic Compounds
- Enantioface-Differentiating Epoxidation of Alkylidenemalononitriles with Molecular Oxygen, catalyzed by Chiral Tertiary Amines
- Formic Acid Reduction. XXVIII. Kinetic Studies on the Formic Acid Reduction of 1,1'-Benzylidenedipiperidine
- A New Insertion Reaction of Diazoalkanes with Dialkylaminomethyl Esters of Dialkyldithiocarbamic Acid and of Ethylxanthic Acid
- Chlorinolyses of Alkyl (or Aryl) Phthalimidomethyl Sulfoxides with Sulfuryl Chloride, Chlorine and Thionyl Chloride
- Nucleophilic Substitution of Alkyl (or Aryl) Imidomethyl Sulfones. A New Convenient Synthesis of Alkane (or Arene) sulfinates
- Decarboxylation Reaction. VIII. Reaction of Electron-deficient Carbon-Carbon Double Bonds with Trichloroacetic Acid. A Unique 1,1-Dichlorocyclopropane Formation through β-Trichloromethylation
- Formic Acid Reduction. XXVI. α, β-Reduction of Conjugated Nitriles with Formic Acid
- Decarboxylation Reactions. V. Reaction of N-Benzylideneanilines with Propiolic Acid
- Formic Acid Reduction. XXIV. Path of the Reductive Fission of the Centered β-Carbon Bond of Alkylidenebisketones
- Formic Acid Reduction. XXIII. Kinetic Studies on the Formic Acid Reduction of Carbon-Carbon Double Bond Adjacent to Carbonyl
- Formic Acid Reduction. XXII. Reaction of α, N-Diphenylnitrone with Formic Acid
- Formic Acid Reduction. XXI. Reductive Cleavage Reaction of p-Dimethylamino-substituted Triphenylmethanes induced by Formate
- Formic Acid Reduction. XX. Reduction of 2-Benzylidene-1,3-indandiones
- Formic Acid Reduction. XIX. Formic Acid Reduction of 4-Dialkylaminosubstituted Nitro-, Nitroso-, Azoxy-and Azobenzenes
- Formic Acid Reduction. XXVIII. Kinetic Studies on the Formic Acid Reduction of 1,1'-Benzylidenedipiperidine
- Preparation of N-Alkylthiomethyl Derivatives of Hydroxylamines
- N-[(N-Nitrosoalkylamino) methyl] carbamates as New and Convenient Diazoalkane-generating Agents
- Thermal and Photochemical Behaviors of N-[(N-Nitrosobenzylamino)-methyl] benzamide in Acidic Media
- Preparations of N-Alkylthiomethyl and N-Amidomethyl Derivatives of Amino Acids
- Chemical Behaviors of 1,1'-Diacetyl-1,1', 4,4'-tetrahydro-4,4'-bipyridine toward Organic Hydrogen Acceptors
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- Formic Acid Reduction. XIII. Formate Reaction of the Compounds possessing the Carbon Bound to Both Oxygen and Nitrogen
- Catalytic Hydrogenation of Tetrahydro-4H-1,3-oxazin-4-ones and 4-Oxazolidinones
- Catalytic Hydrogenolyses of Benzylidene Compounds Bound to Two Oxygens, Two Nitrogens and Both Oxygen and Nitrogen
- Catalytic Hydrogenation of Hydroamide in the Presence of Ammonia and of Butylamine
- Formic Acid Reduction. XXVIII. Kinetic Studies on the Formic Acid Reduction of 1,1'-Benzylidenedipiperidine
- Formic Acid Reduction. XXVIII. Kinetic Studies on the Formic Acid Reduction of 1,1'-Benzylidenedipiperidine
- Formic Acid Reduction. XXVIII. Kinetic Studies on the Formic Acid Reduction of 1,1'-Benzylidenedipiperidine
- Formic Acid Reduction. XXVIII. Kinetic Studies on the Formic Acid Reduction of 1,1'-Benzylidenedipiperidine
- Formic Acid Reduction. XXVIII. Kinetic Studies on the Formic Acid Reduction of 1,1'-Benzylidenedipiperidine
- Formic Acid Reduction. XXVIII. Kinetic Studies on the Formic Acid Reduction of 1,1'-Benzylidenedipiperidine
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- Pyrrolidine-Forming 1,3-Dipolar Cycloaddition of N-(Phenylthiomethyl)-α-amino Acid Esters
- A New Method for the Introduction of Arylthio Groups at the α-Position of Alicyclic Amines
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- オクテット
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- Reactions of 2,2,2-Trichloroethylamines with Grignard Reagents and Alkyllithiums
- 56 ピロリジジンアルカロイドの簡便な新合成法
- A New Route to 4-Unsubstituted β-Lactams through Ureidomethylation of Ketene Silyl Acetals
- New Syntheses of α-N-Alkylacetamidomethylated Carbonyl Compounds
- N-Alkylamidomethylation at Electron-rich Carbons in the 1,3,5-Trialkylhexahydro-1,3,5-triazine-Acetyl Chloride System
- One Step Syntheses of Adenine, Xanthine and Guanine from Phenylazomalonic Acid Derivatives
- One Step Syntheses of Hypoxanthines from 2-Cyano-2-phenylazoacetamides
- Facile Syntheses of Xanthines from Uric Acids
- Monobromination of Cyanoacetamides and Amidinoacetamide with Molecular Bromine
- Formic Acid Reduction. XVIII. Formic Acid Reaction of p-(Dialkylamino) azobenzenes
- Formic Acid Reduction. XVL. Mechanism of the N-Methylation of p-Phenylenediamine Derivatives with Formates
- Reaction of Amide Homologs. XXVI. On the Products obtained from the Reaction of N-Alkylphenylacetamides with Phosphoryl Chloride
- Facile Syntheses of Hypoxanthine and Adenine
- Azole Series. III. Reactions of 2-Acylamino-2-cyanoacetamides leading to 5-Aminooxazole-4-carboxamides and to Oxazolo [5,4-d] pyrimidines
- Azole Series. II. Reactions of 2-Acylamino-2-cyanoacetamides leading to 5-Acylaminooxazole-4-carboxamides and to Oxazolo [5,4-d] pyrimidines
- Reaction of N-(Butoxymethyl) dialkylamines and N, N'-Methylenebis-(dialkylamine)s with N-(1-Cyclohexen-1-yl) dialkylamines
- A Novel 2,3-Pyrrolidinedione Ring Closure of 1,1,1,5,5,5-Hexachloro-4-dimethylamino-3,3-dimethyl-2-pentanone
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- Decarboxylation Reactions. VI. Reaction of α-Arylmethyleneamino-substituted Derivatives of Pyridine, Quinoline, and Isoquinoline with Trichloroacetic Anhydride
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- Reaction of Schiff Bases with Trichloroacetyl Chloride in the Presence of Triphenylphosphine
- Decarboxylation Reactions. IV. Reaction of Schiff Bases with Trichloroacetic Anhydride
- Reaction of 1-Pyrrolidino-1-cyclohexene with Imidoyl Chlorides and a Route to Producing Phenanthridines
- Intramolecular Aldol Condensations of the Reaction Products formed from 2,4-Pentanedione and Aldehydes
- Vapor-Liquid Equilibrium for Formic Acid-Triethylamine System Examined by the Use of a Modified Still. Formic Acid-Trialkylamine Azeotropes
- N-[(N-Nitrosoarylamino) methyl] succinimide as a New Agent Generating Aromatic Diazotate
- Decarboxylation Reactions. I. Reaction of Enamines with Carboxylic Acids
- 鵜飼貞二先生を悼む
- Reduction of 2,2,2-Trichloroethylamines with Lithium Aluminum Hydride
- Reactions of 1-Trichloromethyl-substituted Amines with Potassium tert-Butoxide
- 新しい合成反応および試薬
- Chlorinolyses of Alkyl (or Aryl) Phthalimidomethyl Sulfides with Sulfuryl Chloride or Chlorine in the Presence and the Absence of Acetic Anhydride
- Formic Acid Reduction. XXVII. Selective Reduction of Carbon-Carbon Double Bonds conjugated with Nitro and Sulfonyl Groups
- 「速報をどう考える」のパネルを読んで : その2
- 新しいジアゾアルカン生成試薬および安定ジアゾアルカン試薬について
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- N-[(N-Nitrosobenzylamino) methyl] benzamide as a Direct Benzylating Agent
- Decarboxylation Reactions. II. Reaction of Conjugated Unsaturated Ketones and Nitriles with Carboxylic Acids
- トリクロロ酢酸イオンの脱酸素を含むトリクロロ酢酸およびその無水物の反応
- 新しいジアゾアルカン生成試薬および安定ジアゾアルカン試薬について
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- Synthesis of α-Thio, α-Sulfinyl, and α-Sulfonyl-substituted Nitrosamines
- Alkylation of Phthalimidines
- Synthesis of N-(Alkylaminomethyl) amides