Formic Acid Reduction. XXIII. Kinetic Studies on the Formic Acid Reduction of Carbon-Carbon Double Bond Adjacent to Carbonyl
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概要
- 論文の詳細を見る
Kinetic manner was introduced into mechanistic studies on the formic acid reduction of carbon-carbon double bond adjacent to carbonyl induced by the formate reagent, TEAF, 5HCO_2H・2NEt_3. Kinetic data obtained by the use of 1,3-dimethyl-5-benzyli-denebarbituric acid as a representative, the second order kinetics, the large negative entropy of activation, the isotope effect (2.79) and the positive ρ-value (+1.00) of the Hammett equation, suggest one step path, which proceeds by the attack of HCO_2-・HN^^+Et_3 involving the push-pull mechanism of ring system of a transition state.
- 社団法人日本薬学会の論文
- 1976-04-25
著者
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関屋 実
School Of Pharmaceutical Sciences University Of Shizuoka
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鈴木 邦夫
School Of Pharmaceutical Sciences University Of Shizuoka
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鈴木 邦夫
Shizuoka College of Pharmacy
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関屋 実
Shizuoka College of Pharmacy
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府川 秀道
Shizuoka College of Pharmacy
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奥川 徹
Shizuoka College of Pharmacy
関連論文
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