Synthesis of α-Thio, α-Sulfinyl, and α-Sulfonyl-substituted Nitrosamines
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概要
- 論文の詳細を見る
A new route to the preparation of α-alkyl (or aryl) thiosubstituted nitrosamines has been provided by nitrosation of alkylaminomethyl alkyl (or aryl) sulfides obtained simply from primary amine hydrochlorides, formaldehyde, and alkyl (or aryl) thioalcohols. By oxidation with metaperiodate and permanganate the corresponding sulfoxides and sulfones have been obtained, respectively. Compositions of the syn and anti isomers of the nitrosamines are determined by NMR technique.
- 公益社団法人日本薬学会の論文
- 1977-11-25
著者
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関屋 実
School Of Pharmaceutical Sciences University Of Shizuoka
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寺尾 良保
Shizuoka College of Pharmacy
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関屋 実
Shizuoka College of Pharmacy
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松永 宏二
Shizuoka College Of Pharmacy
関連論文
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- Reactions of 2,2-Dichlorovinyl and 2,2-Dichlorovinylidene Sulfides with Butyllithium
- Thermal Rearrangements of Allyl 2,2-Dichloro-, 1,2-Dichloro- and 1,2,2-Trichloro-substituted Vinyl Sulfides
- Novel Rearrangements of α-N-Alkylamido-substituted Sulfides and Sulfones
- Syntheses and Reactions of Phenylthio-and Propylthioacetylenic Compounds
- Enantioface-Differentiating Epoxidation of Alkylidenemalononitriles with Molecular Oxygen, catalyzed by Chiral Tertiary Amines
- Formic Acid Reduction. XXVIII. Kinetic Studies on the Formic Acid Reduction of 1,1'-Benzylidenedipiperidine
- A New Insertion Reaction of Diazoalkanes with Dialkylaminomethyl Esters of Dialkyldithiocarbamic Acid and of Ethylxanthic Acid
- Chlorinolyses of Alkyl (or Aryl) Phthalimidomethyl Sulfoxides with Sulfuryl Chloride, Chlorine and Thionyl Chloride
- Nucleophilic Substitution of Alkyl (or Aryl) Imidomethyl Sulfones. A New Convenient Synthesis of Alkane (or Arene) sulfinates
- Decarboxylation Reaction. VIII. Reaction of Electron-deficient Carbon-Carbon Double Bonds with Trichloroacetic Acid. A Unique 1,1-Dichlorocyclopropane Formation through β-Trichloromethylation
- Formic Acid Reduction. XXVI. α, β-Reduction of Conjugated Nitriles with Formic Acid
- Decarboxylation Reactions. V. Reaction of N-Benzylideneanilines with Propiolic Acid
- Formic Acid Reduction. XXIV. Path of the Reductive Fission of the Centered β-Carbon Bond of Alkylidenebisketones
- Formic Acid Reduction. XXIII. Kinetic Studies on the Formic Acid Reduction of Carbon-Carbon Double Bond Adjacent to Carbonyl
- Formic Acid Reduction. XXII. Reaction of α, N-Diphenylnitrone with Formic Acid
- Formic Acid Reduction. XXI. Reductive Cleavage Reaction of p-Dimethylamino-substituted Triphenylmethanes induced by Formate
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- Formic Acid Reduction. XIX. Formic Acid Reduction of 4-Dialkylaminosubstituted Nitro-, Nitroso-, Azoxy-and Azobenzenes
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- Formic Acid Reduction. XIII. Formate Reaction of the Compounds possessing the Carbon Bound to Both Oxygen and Nitrogen
- Catalytic Hydrogenation of Tetrahydro-4H-1,3-oxazin-4-ones and 4-Oxazolidinones
- Catalytic Hydrogenolyses of Benzylidene Compounds Bound to Two Oxygens, Two Nitrogens and Both Oxygen and Nitrogen
- Catalytic Hydrogenation of Hydroamide in the Presence of Ammonia and of Butylamine
- Formic Acid Reduction. XXVIII. Kinetic Studies on the Formic Acid Reduction of 1,1'-Benzylidenedipiperidine
- Formic Acid Reduction. XXVIII. Kinetic Studies on the Formic Acid Reduction of 1,1'-Benzylidenedipiperidine
- Formic Acid Reduction. XXVIII. Kinetic Studies on the Formic Acid Reduction of 1,1'-Benzylidenedipiperidine
- Formic Acid Reduction. XXVIII. Kinetic Studies on the Formic Acid Reduction of 1,1'-Benzylidenedipiperidine
- Formic Acid Reduction. XXVIII. Kinetic Studies on the Formic Acid Reduction of 1,1'-Benzylidenedipiperidine
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- A New Method for the Introduction of Arylthio Groups at the α-Position of Alicyclic Amines
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- オクテット
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- 56 ピロリジジンアルカロイドの簡便な新合成法
- A New Route to 4-Unsubstituted β-Lactams through Ureidomethylation of Ketene Silyl Acetals
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- N-Alkylamidomethylation at Electron-rich Carbons in the 1,3,5-Trialkylhexahydro-1,3,5-triazine-Acetyl Chloride System
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- One Step Syntheses of Hypoxanthines from 2-Cyano-2-phenylazoacetamides
- Facile Syntheses of Xanthines from Uric Acids
- Monobromination of Cyanoacetamides and Amidinoacetamide with Molecular Bromine
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- Thiocarbonyl Ylides. VI, New Generation of Thiocarbonyl Ylides from Organosilicon Compounds Containing Sulfur and Their 1,3-Cycloadditions(Organic,Chemical)
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- Enzymes and Catalysts. I. Pig Liver Esterase-Catalyzed Hydrolysis of Heterocyclic Diesters(Organic,Chemical)
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- Reaction of N, N-Dialkylaminomethyl Arenesulfonates with Diazoalkanes
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- Reaction of Schiff Bases with Trichloroacetyl Chloride in the Presence of Triphenylphosphine
- Decarboxylation Reactions. IV. Reaction of Schiff Bases with Trichloroacetic Anhydride
- Reaction of 1-Pyrrolidino-1-cyclohexene with Imidoyl Chlorides and a Route to Producing Phenanthridines
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- Vapor-Liquid Equilibrium for Formic Acid-Triethylamine System Examined by the Use of a Modified Still. Formic Acid-Trialkylamine Azeotropes
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- Decarboxylation Reactions. I. Reaction of Enamines with Carboxylic Acids
- 鵜飼貞二先生を悼む
- Reduction of 2,2,2-Trichloroethylamines with Lithium Aluminum Hydride
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- Chlorinolyses of Alkyl (or Aryl) Phthalimidomethyl Sulfides with Sulfuryl Chloride or Chlorine in the Presence and the Absence of Acetic Anhydride
- Formic Acid Reduction. XXVII. Selective Reduction of Carbon-Carbon Double Bonds conjugated with Nitro and Sulfonyl Groups
- 「速報をどう考える」のパネルを読んで : その2
- 新しいジアゾアルカン生成試薬および安定ジアゾアルカン試薬について
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- トリクロロ酢酸イオンの脱酸素を含むトリクロロ酢酸およびその無水物の反応
- 新しいジアゾアルカン生成試薬および安定ジアゾアルカン試薬について
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- Alkylation of Phthalimidines
- Synthesis of N-(Alkylaminomethyl) amides