A New Synthesis of 3-Oxosapriparaquinone, a Diterpene from Salvia prionitis HANCE (Libiatae)

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概要

• 論文の詳細を見る

• 5,8,11,13-Abietatetraen-3-one (3) and its 12-methoxy derivative (7) were oxidized to the corresponding 3,7-diones, which were rearranged respectively into 2-isopropyl-6-methyl-5-(4-methyl-3-oxopentyl)naphthalene (6) and its 12-methoxy derivative (10) by sodium borohydride reduction and subsequent dehydration with boron trifluoride etherate. Compound 10 was further converted into 3-oxosapriparaquinone (1) via 5-(3-acetoxy-4-methylpentyl)-2-isopropyl-6-methyl-3,4-naphthoquinone (14).

• 社団法人日本薬学会の論文
• 1996-08-15

著者

• 高石 喜久

  徳島大院薬

• Takeda Yoshio

  Faculty of Pharmacy, Yasuda Womens University

• Takeda Y

  Fac. Of Integrated Arts And Sciences Univ. Of Tokushima

• Takeda Y

  Faculty Of Integrated Arts And Sciences The University Of Tokushima

• MATSUMOTO Takashi

  Faculty of Engineering, Yamanashi University

• SOH Kimiko

  Faculty of Integrated Arts and Sciences, The University of Tokushima

• MATSUMURA Hiroyuki

  Faculty of Integrated Arts and Sciences, The University of Tokushima

• IMAI Sachihiko

  Suzugamine Women's College

• Soh K

  Faculty Of Integrated Arts And Sciences The University Of Tokushima

• Soh Kimiko

  Faculty Of Integrated Arts And Sciences The University Of Tokushima

• Takeda Yoshio

  Faculty Of General Arts And Sciences The Tokushima University

• Matsumoto Takashi

  Faculty Of Engineering Department Of Electronic Engineering Yamanashi University

• Matsumoto T

  Department Of Microbiology Tohoku Pharmceutical University

• Imai S

  Niigata Univ. Pharmacy And Applied Life Sci. Niigata Jpn

• Imai Sachihiko

  Suzugamine Women's College

• Matsumoto T

  Faculty Of Integrated Arts And Sciences The University Of Tokushima

• MATSUMURA Hiroyuki

  School of Agricultural Sciences

• Matsumoto Takashi

  Faculty Of Agriculture Shinshu University

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