Effect of Sodium Dodecyl Sulfate Concentration on Photooxidation of Methyl Orange Sensitized by Tetraphenylporphyrin
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概要
- 論文の詳細を見る
The effect of sodium dodecyl sulfale (SDS) concentration on the efficiency of the photooxidation of Methyl Orange sensitized by tetraphenylporphyrin (TPP) in the surfactant solution was investigated. It was found that the efficiency of the photooxidation is lower above the critical micelle concentration of SDS-TPP mixed solution (cmc_<mix>) than below the cmc<mix>. By taking into consideration the formation of an oligomer complex between one TPP molecule and several SDS molecules below the cmc<mix>, it was possible to explain the relatively lower efficiency above the cmc<mix> in terms of the lower reactivity between singlet oxygen produced by the excited TPP and methyl orange (MO) in the less polar environment on the micellar surface.
- 公益社団法人日本薬学会の論文
- 1988-01-25
著者
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宮嶋 孝一郎
Faculty of Pharmaceutical Sciences, Kyoto University
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中垣 正幸
Faculty of Pharmaceutical Sciences, Kyoto University
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半田 哲郎
京大・薬
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中垣 正幸
東京コロイド科学研究所
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宮嶋 孝一郎
大阪薬科大学招聘教授
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半田 哲郎
Gifu Pharmaceutical University
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井上 和博
Faculty Of Pharmaceutical Sciences Kyoto University
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小松 裕明
Faculty of Pharmaceutical Sciences, Kyoto University
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宮嶋 孝一郎
京大・薬
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小松 裕明
Division Of Drugs Osaka Branch National Institute Of Health Sciences
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中垣 正幸
Tokyo Insitute Of Colloid Science
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宮嶋 孝一郎
Faculty Of Pharmaceutical Sciences Kyoto University
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