An Efficient Total Synthesis of (±)-Epilupinine and (±)-Lupinine from a Common Quinolizidine Intermediate

スポンサーリンク

概要

論文の詳細を見る
A common intermediate, the quinolizidine (5) obtained by annulation of a cyclic thioimidate (3) with Nazarov's reagent (4) in the presence of mercuric chloride, was stereospecifically transformed into (±)-epiupinine (1) and (±)-lupinine (2).
社団法人日本薬学会の論文
1986-11-25

著者

関連論文

Synthetic Studies of Azaflavonoids. I. Studies on the Synthesis of 5-Azaflavone
8,13-Diazagona-1,3,5 (10)-triene-12-ones, Synthesis and Stereochemistry
A Stereocontrolled Synthesis of (±)-Emetine and (±)-Protoemetinol by Intramolecular Michael Reaction
Chemistry of 2-Methoxy-2,5-cyclohexadienone. V. Photochemical Rearrangement and Oxidation of 2-Methoxy-4-methyl-4-phenyl-2-cyclohexenone and 2-Methoxy-4-methyl-4-phenyl-2,5-eyclohexadienone(Organic,Chemical)
薬理活性志向のヘテロ環の合成研究
Synthesis in the Diazasteroid Group. XX. Synthesis of the 5,14-Diazasteroid System(Organic,Chemical)
チオアミド官能基の特性を利用する複素環合成
An Efficient Total Synthesis of (±)-Epilupinine and (±)-Lupinine from a Common Quinolizidine Intermediate
Favorskii Reaction of 2-Bromobicyclo[3.3.1]nonan-3-one
Reaction of Aliphatic Dicarboxylic Acids with Acyl Chlorides in the Presence of Aluminum Chloride
Ketene-S, N-acetals as Synthetic Intermediates for Heterocycles. Reaction of Ketene-S, N-acetals with Aryl Isocyanates
Chemistry of 2-Methoxy-2,5-cyclohexadienone. IV. Photochemistry of 2-Methoxy-4,4-diphenyl-2,5-cyclohexadienone and 4-Dichloromethyl-2-methoxy-4-methyl-2,5-cyclohexadienone
Reduction of Vinylogous Thioesters with Lithium Aluminum Hydride. II. Reduction of 2-Methyl-3-phenylthio-5-substituted-2-cyclopentenones
Reduction of Vinylogous Thioesters with Lithium Aluminum Hydride. I. Reduction of β-Phenylthio-α, β-unsaturated Cyclic Ketones
Chemistry of 2-Methoxy-2,5-cyclohexadienones. III. Syntheses of 2-Methoxy-4,4-diphenyl-2,5-cyclohexadienone and 4-Dichloromethyl-2-methoxy-4-methyl-2,5-cyclohexadienone
Structural Modification of Bioactive Compounds. II. Syntheses of Aminophosphonoic Acids
Chemistry of 2-Methoxy-2,5-cyclohexadienones. II. Oxidation of 2-Methoxy-4,4-dimethyl-2,5-cyclohexadienone
Synthesis in the Diazasteroid Group. XXI. An Alternative Synthesis of the 8,16-Diazasteroid System
KETENE-S, N-ACETALS AS SYNTHETIC INTERMEDIATES FOR HETEROCYCLES. A NOVEL SYNTHESIS OF POLYFUNCTIONALIZED PYRIDINE-2-THIONES
Structural Modification of Bioactive Compounds. I. Syntheses of Vitamin D Analogues I
Nitration of 2-Cyclohexenone Derivatives and Some Reactions of the Products
AN EASY SYNTHESIS OF MONOMETHYL MALONATE DERIVATIVES
Activated Lactams. VI. The Cycloaddition Reaction of Cyclic Ketene-S, N-acetals with Dimethyl Acetylenedicarboxylate
The Chemistry of Lactim Ethers. IV. Syntheses of 1,9-and 5,9-Diazasteroid Systems
The Chemistry of Lactim Ethers. II. Reaction of Lactim Ethers with 2-Carbethoxymethyl Piperidines
Acid-catalyzed Cyclization of Chalcones derived from Various Nitrogenous Heteroaromatic Compounds. II
Chemistry of 2-Methoxy-2,5-cyclohexadienones. I. Photochemistry of 2-Methoxy-4,4-dimethyl-2,5-cyclohexadienone
A FACILE SYNTHESIS OF 2-METHOXY-4,4-DIMETHYL-2,5-CYCLOHEXADIENONE VIA 5,5-DIMETHYL-2-NITRO-1,3-CYCLOHEXADIENOL
Michael Addition of [1H] Pyrrole
Synthesis in the Diazasteroid Group. XIX. Synthesis of the 9,13-Diazasteroid System
The Chemistry of Lactim Ethers. V. Reaction of Lactim Thioethers with β-Aminoesters
Acid-catalyzed Cyclization of Chalcones derived from Various Nitrogenous Heteroaromatic Compounds
A Convenient Synthesis of Monocyclic β-Lactams by Means of Solid-Liquid Phase Transfer Reactions
Synthesis in the Diazasteroid Group. XV. Syntheses of the 5,9- and 8,13-Diazasteroids
Synthesis in the Diazasteroid Group. XIV. Synthesis of the 13,15-Diazasteroid System
Reaction of Lactim Thioethers with 1-Carbethoxymethyl-1,2,3,4-tetrahydroisoquinoline
Synthesis of 8,10-Diaza-estrane
Synthetic Studies of Azaflavonoids. II. Synthesis of 6-Azaflavonoids
Studies on O-Alkylated Imides. II. Some Reactions of O-Ethyl Succinimide and O-Ethyl 4,4-Dimethyl-glutarimide
Reduction of O-Alkylated Imides
Synthesis of Zwitterionic Pyridazine Derivatives. I
Synthesis in the Diazasteroid Group. XVIII. Syntheses of the 9,17-Diazasteroid System
Synthesis in the Diazasteroid Group. XVII. Syntheses of the 4,11-Diazasteroid System
New Synthetic Routes to Carbohydrates by the Use of Telomers of Vinylene Carbonate with Polyhalomethanes
チオアミド官能基の特性を利用する複素環合成
二重不斉化反応による光学純度累進効果を活用する有機合成
非キラルなクロマトグラフィーにおける光学分割現象
高選択的なヘテロ環化反応の開発と生物活性物質の合成への応用
2級アリルアルコールに対する分子内アミノ付加反応を基盤とする含窒素生物活性物質のキラル合成

もっと見る

スポンサーリンク