二重不斉化反応による光学純度累進効果を活用する有機合成
スポンサーリンク
概要
- 論文の詳細を見る
Sequential and iterative asymmetric reaction on achiral substrates with two prochiral centers caused an enantiomeric enhancement and its synthetic application to C<SUB>2</SUB> symmetric azacycloalkanes and 2, 6 disubstituted piperidines is described. Repeated asymmetric dihydroxylation (AD) for terminal olefins also improved stereoselectivity (ee) and a number of syntheses of alkaloids are demonstrated.
- 社団法人 有機合成化学協会の論文
- 1999-10-01
著者
関連論文
- 薬理活性志向のヘテロ環の合成研究
- An Efficient Total Synthesis of (±)-Epilupinine and (±)-Lupinine from a Common Quinolizidine Intermediate
- Ketene-S, N-acetals as Synthetic Intermediates for Heterocycles. Reaction of Ketene-S, N-acetals with Aryl Isocyanates
- Synthesis in the Diazasteroid Group. XXI. An Alternative Synthesis of the 8,16-Diazasteroid System
- KETENE-S, N-ACETALS AS SYNTHETIC INTERMEDIATES FOR HETEROCYCLES. A NOVEL SYNTHESIS OF POLYFUNCTIONALIZED PYRIDINE-2-THIONES
- Activated Lactams. VI. The Cycloaddition Reaction of Cyclic Ketene-S, N-acetals with Dimethyl Acetylenedicarboxylate
- The Chemistry of Lactim Ethers. IV. Syntheses of 1,9-and 5,9-Diazasteroid Systems
- The Chemistry of Lactim Ethers. II. Reaction of Lactim Ethers with 2-Carbethoxymethyl Piperidines
- The Chemistry of Lactim Ethers. V. Reaction of Lactim Thioethers with β-Aminoesters
- A Convenient Synthesis of Monocyclic β-Lactams by Means of Solid-Liquid Phase Transfer Reactions
- Synthesis in the Diazasteroid Group. XV. Syntheses of the 5,9- and 8,13-Diazasteroids
- Synthesis in the Diazasteroid Group. XIV. Synthesis of the 13,15-Diazasteroid System
- Reaction of Lactim Thioethers with 1-Carbethoxymethyl-1,2,3,4-tetrahydroisoquinoline
- Synthesis of 8,10-Diaza-estrane
- Synthesis in the Diazasteroid Group. XVIII. Syntheses of the 9,17-Diazasteroid System
- Synthesis in the Diazasteroid Group. XVII. Syntheses of the 4,11-Diazasteroid System
- チオアミド官能基の特性を利用する複素環合成
- 二重不斉化反応による光学純度累進効果を活用する有機合成
- 非キラルなクロマトグラフィーにおける光学分割現象
- 高選択的なヘテロ環化反応の開発と生物活性物質の合成への応用
- 2級アリルアルコールに対する分子内アミノ付加反応を基盤とする含窒素生物活性物質のキラル合成