Synthesis of ecdysone.II.Synthesis of and Stereochemistry of 2β, 3β-Dihydroxycholestan-6-ones and Their Derivatives
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概要
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2β, 3β-Dihydroxycholestan-6-ones and their derivatives were prepared and their stereo chemistry was studied. In 2β, 3β-dihydroxy-or 2β, 3β-diacetoxycholestan-6-ones, equilibrium mixture consisted of 5α-and 5β-compound at the ratioof 3 : 2. On the other hand, 5α-compound was found to be exclusively stable in 2β, 3β-dihydroxycholestan-6-one acetonides.
- 社団法人日本薬学会の論文
- 1967-04-25
著者
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沢井 政信
Research Laboratory Teikoku Hormone Mfg. Co. Ltd.
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森 弘
Chemical Research Department Teikoku Hormone Mfg. Co. Ltd.
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柴田 健雄
Research Laboratory, Teikoku Hormone Mfg. Co., Ltd.
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森 弘
Research Laboratory, Teikoku Hormone Mfg. Co., Ltd., Shimosakunobe, Kawasaki
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常田 清
Research Laboratory, Teikoku Hormone Mfg. Co., Ltd.
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柴田 健雄
Research Department Teikoku Hormone Mfg. Co. Ltd.
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常田 清
Research Laboratory Teikoku Hormone Mfg. Co. Ltd.
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