Studies on Steroidal Compounds. IX. Preparation of 17α-Chloro Steroids.
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概要
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Some hydroxy-steroids were transformed into the corresponding chloro-steroids with Walden inversion, when treated with sulfuryl chloride in pyridine ; testosterone (I), 4-chlorotestosterone (IV), 17β-hydroxy-5α-androstan-3-one (V), 5α-androstane-3β, 17β-diol 3-acetate (VIII), and estradiol 3-benzoate (IX) were introduced to the corresponding 17α-chloro compounds, II, III, VI, VIIa, and X, respectively. From androsterone (XI) and isoandrosterone (XIV) were obtained 3β-chloro-5α-androstan-17-one (XII) and 3α-chloro-5α-androstan-17-one (XIII) respectively.
- 公益社団法人日本薬学会の論文
- 1963-11-25
著者
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森 弘
Chemical Research Department Teikoku Hormone Mfg. Co. Ltd.
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森 弘
Research Laboratory, Teikoku Hormone Mfg. Co., Ltd., Shimosakunobe, Kawasaki
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和田 俊洋
Research Laboratory, Teikoku Hormone Mfg. Co., Ltd.
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和田 俊洋
Research Laboratory Teikoku Hormone Mfg. Co. Ltd.
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