Studies on Steroidal Compounds. X. Preparation of 17β-Chloro Steroids.
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概要
- 論文の詳細を見る
17β-Chloro-5α-androstan-3β-ol (VII) and 17β-chloro-5α-androstan-3-one (VI) were prepared. 3β-Hydroxy-5α-androstan-17-one hydrazone (II) was treated with N-chlorosuccinimide in pyridine to give 17-chloro-5α-androst-16-en-3β-ol (IVa), which on hydrogenation with 5% palladium charcoal afforded VII. The chromium trioxide oxidation of VII gave VI. Some observations concerning 17-bromo and 17-iodo compounds (IVb and III) were also written.
- 公益社団法人日本薬学会の論文
- 1963-11-25
著者
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森 弘
Chemical Research Department Teikoku Hormone Mfg. Co. Ltd.
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森 弘
Research Laboratory, Teikoku Hormone Mfg. Co., Ltd., Shimosakunobe, Kawasaki
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常田 清
Research Laboratory, Teikoku Hormone Mfg. Co., Ltd.
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常田 清
Research Laboratory Teikoku Hormone Mfg. Co. Ltd.
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