Further Preparation of Steroidal Diosphenols. II. Synthesis of 2,16α, 17β-and 2,16β, 17β-Trihydroxy-4,4-dimethylandrosta-1,5-dien-3-ones
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概要
- 論文の詳細を見る
2,16β, 17β-Trihydroxy-4,4-dimethylandrosta-1,5-dien-3-one (VI) was prepared from 2,16β, 17β-trihydroxyandrost-5-ene 16,17-acetonide in 4 steps. 2,16α, 17β-Trihydroxy-4,4-dimethylandrosta-1,5-dien-3-one (XVIII) was prepared form 2,17β-dihydroxy-4,4-dimethylandrosta-1,5-dien-3-one (VII) in 8 steps. It was found that the 2,3-ketol was converted to the 2,3-diketone by autoxidation without influence on 16,17-glycol.
- 社団法人日本薬学会の論文
- 1967-02-25
著者
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森 弘
Chemical Research Department Teikoku Hormone Mfg. Co. Ltd.
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柴田 健雄
Research Laboratory, Teikoku Hormone Mfg. Co., Ltd.
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森 弘
Research Laboratory, Teikoku Hormone Mfg. Co., Ltd., Shimosakunobe, Kawasaki
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山田 〓治
Research Laboratory, Teikoku Hormone Mfg. Co., Ltd.
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柴田 健雄
Research Department Teikoku Hormone Mfg. Co. Ltd.
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