Enzymic Oxidation of α, β-Unsaturated Alcohols in the Side Chains of Lignin-related Aromatic Compounds
スポンサーリンク
概要
- 論文の詳細を見る
An enzyme which catalyzed oxidation of the α, β-unsaturated primary alcohol group in the side chain of dehydrodiconiferyl alcohol to the corresponding aldehyde was excreted into the culture media by several molds that degraded synthetic lignin-a dehydrogenation polymer of coniferyl alcohol and lignosulfonte. The enzyme produced by Fusarium solani M-13-1,partially purified by gel filtration, specifically oxidezed α, β-unsaturated alcohols in the side chains of lignin-related aromatic compounds such as coniferyl alcohol, cinnamyl alcohol, dehydrodiconiferyl alcohol and guaiacylglycerol-β-coniferyl ether, but did not oxideze aromatic alcohols such as benzyl o-, m- and p-methoxybenzyl, and vanillyl alcohols or aliphatic alcohols such as methanol, ethanol, butanol. The reaction required one mole of oxygen to oxidize one mole of substrate and produced one mole of hydrogen peroxide. It is suggested that this enzyme also oxidizes α, β-unsaturated alcohol groups in the side chains of high molecular weight lignins.
- 社団法人日本生物工学会の論文
- 1980-06-25
著者
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IWAHARA SHOJIRO
Department of Bioresource Science, Faculty of Agriculture, Kagawa University
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KUWAHARA MASAAKI
Department of Urology, Miyagi Cancer Center
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HIGUCHI Takayoshi
Division of Lignin Chemistry, WOOD RESEARCH INSTITUTE, KYOTO UNIVERSITY
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Higuchi Takayoshi
Division Of Lignin Chemistry Wood Research Institute Kyoto University
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Kuwahara Masaaki
Department Of Urology Miyagi Cancer Center
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Iwahara Shojiro
Department Of Agricultural Chemistry Faculty Of Agriculture Kagawa University
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Jomori Takahito
Department Of Agricultural Chemistry Faculty Of Agriculture Kagawa Univeristy
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NISHIHARA TSUYOSHI
Department of Agricultural Chemistry, Faculty of Agriculture, Kagawa University
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Nishihara Tsuyoshi
Department Of Agricultural Chemistry Faculty Of Agriculture Kagawa University
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Kuwahara Masaaki
Department Of Agricultural Chemistry Kyoto University
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Kuwahara Masaaki
Department Of Food Science Faculty Of Agriculture Kagawa University
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