Synthesis of p-Coumar-, Coniferyl- and Sinap Aldehydes
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概要
- 論文の詳細を見る
この論文は国立情報学研究所の学術雑誌公開支援事業により電子化されました。p-Coumar-, coniferyl- and sinap aldehydes were synthesized in good yields by new two synthetic methods. 1) The aldehydes were prepared by a two-carbon homologation of p-hydroxybenzaldehyde, vanillin and syringaldehyde with 2, 4, 4, 6-tetramethyl-5, 6-dihydro-1, 3-oxazine in the presence of n-butyllithium in anhydrous tetrahydrofurane at -77℃. 2) The aldehydes were also prepared by reduction of the corresponding p-hydroxycinnamic acid chlorides with lithium tri-t-butoxyaluminohydride in anhydrous diglyme at -77℃.
- 京都大学の論文
- 1974-02-28
著者
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Nakatsubo Fumiaki
Division Of Forest And Biomaterials Science Graduate School Of Agriculture Kyoto University
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Nakatsubo Fumiaki
Division Of Lignin Chemistry Wood Research Institute Kyoto University
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Higuchi Takayoshi
Division Of Lignin Chemistry Wood Research Institute Kyoto University
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NAKAMURA Yoshiki
Division of Lignin Chemistry, WOOD RESEARCH INSTITUTE, KYOTO UNIVERSITY
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Nakamura Yoshiki
Division Of Lignin Chemistry Wood Research Institute Kyoto University
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