Production of Methyl, Dimethyl, Ethyl, Chloro-, Fluoro-, and Hydroxyl Derivatives of Catechol from Thirteen Aromatic Amines by the Transpositional Mutant B-9 of the Aniline-Assimilating Pseudomonas Species AW-2
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概要
- 論文の詳細を見る
Resting cells of the transpositional mutant strain B-9,which was obtained from the anilline-assimilating Pseudomonas sp. AW-2 and produced catechol from aniline, exhibited the ability to oxidize 16 aromatic amines among 26 tested. Thirteen products from the 16 amines were purified and crystallized. Analytical data including mass and nuclear magnetic resonance spectra of the products showed that methyl, dimethyl, ethyl, chloro-, fluoro-, and hydroxyl derivatives of aniline were convereted to the corresponding catechols. In particular, catechols were synthesized from o-, m-, and p-toluidine, p-fluoroaniline, and m-aminophenol at a conversion rate of 100%. It was revealed that strain B-9 cells exhibited extensive substrate specificity for aromatic amines, regardless of the position of substituent groups in their isomers.
- 社団法人日本生物工学会の論文
- 1997-09-25
著者
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Murakami Shuichiro
Laboratory of Applied Microbiology, Department of Biofunctional Chemistry, Faculty of Agriculture, K
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Aoki Kenji
Laboratory of Applied Microbiology, Department of Biofunctional Chemistry, Faculty of Agriculture, K
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Aoki K
Department Of Applied Biological Chemistry Graduate School Of Agricultural Science Kobe University
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KODAMA Noriko
Division of Science of Biological Resources, Graduate School of Science and Technology, Kobe Univers
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TAKENAKA Shinji
Division of Science of Biological Resources, Graduate School of Science and Technology, Kobe Univers
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Shinke R
Laboratory Of Bio-functional Chemistry Division Of Bioscience The Graduate School Of Science And Tec
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Shinke Ryu
Division Of Science Of Biological Resources The Graduate School Of Science And Technology
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Kodama Noriko
Division Of Science Of Biological Resources Graduate School Of Science And Technology Kobe Universit
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MURAKAMI SHUICHIROU
Laboratory of Applied Microbiology, Department of Biofunctional Chemistry, Faculty of Agriculture
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SHINKE RYU
Laboratory of Applied Microbiology, Department of Biofunctional Chemistry, Faculty of Agriculture
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Murakami Shuichiro
Dep. Of Bioscience Biotechnology And Agrochemistry Fac. Of Agriculture Meiji Univ.
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Takenaka Shinji
Department Of Agrobioscience Graduate School Of Agricultural Science Kobe University
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Takenaka Shinji
Division Of Science Of Biological Resources The Graduate School Of Science And Technology:kobe Unive
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Shinke Ryu
Laboratory Of Bio-functional Chemistry Division Of Bioscience The Graduate School Of Science And Tec
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